Applied Catalysis B: Environmental, volume 339, pages 123103
Synergistic role of Cu-C and Cu-N dual bonding of nanostructured g-C3N4/Cu2SnS3 photocatalysts for efficient CO2 conversion to CO
1
Department of Chemistry, Faculty of Science, Assiut University, Assiut 71516, Egypt
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Publication type: Journal Article
Publication date: 2023-12-01
Journal:
Applied Catalysis B: Environmental
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 22.1
ISSN: 09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
Herein, a 2D/0D g-C3N4/Cu2SnS3 heterostructure is successfully constructed via the facile calcination method, and its application to photocatalytic CO2 conversion is demonstrated for the first time. The fabricated g-C3N4/Cu2SnS3 nanocomposite is featured with its unique Cu-C and Cu-N dual chemical bond at the interface. The engineered g-C3N4/Cu2SnS3 nanocomposites record a superior CO production rate of 18.2 μmol∙g−1∙h−1 with an apparent quantum yield of 2.2% at 500 nm of light illumination, which is the highest among g-C3N4/ternary metal sulfide photocatalysts to the best of our knowledge. This notable improvement is attributed to the effective incorporation of Cu2SnS3 nanoparicles onto the surfaces of ultra-thin g-C3N4 and, the formation of Cu-N and Cu-C dual bonds at the interface. This helps not only the activation of interface defect-mediated Z-scheme conduction but also supplies highly reactive Cu sites in the Cu2SnS3 nanoparticles for efficient photocatalytic CO2 conversion.
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Citations by publishers
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- We do not take into account publications without a DOI.
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Omr H. A. E. et al. Synergistic role of Cu-C and Cu-N dual bonding of nanostructured g-C3N4/Cu2SnS3 photocatalysts for efficient CO2 conversion to CO // Applied Catalysis B: Environmental. 2023. Vol. 339. p. 123103.
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Omr H. A. E., Raghunath P., Feng S., Lin M. C., Lee H. Synergistic role of Cu-C and Cu-N dual bonding of nanostructured g-C3N4/Cu2SnS3 photocatalysts for efficient CO2 conversion to CO // Applied Catalysis B: Environmental. 2023. Vol. 339. p. 123103.
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TY - JOUR
DO - 10.1016/j.apcatb.2023.123103
UR - https://doi.org/10.1016/j.apcatb.2023.123103
TI - Synergistic role of Cu-C and Cu-N dual bonding of nanostructured g-C3N4/Cu2SnS3 photocatalysts for efficient CO2 conversion to CO
T2 - Applied Catalysis B: Environmental
AU - Omr, Hossam A E
AU - Raghunath, Putikam
AU - Feng, Shien-Ping
AU - Lin, M. C.
AU - Lee, Hyeonseok
PY - 2023
DA - 2023/12/01 00:00:00
PB - Elsevier
SP - 123103
VL - 339
SN - 0926-3373
SN - 1873-3883
ER -
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@article{2023_Omr,
author = {Hossam A E Omr and Putikam Raghunath and Shien-Ping Feng and M. C. Lin and Hyeonseok Lee},
title = {Synergistic role of Cu-C and Cu-N dual bonding of nanostructured g-C3N4/Cu2SnS3 photocatalysts for efficient CO2 conversion to CO},
journal = {Applied Catalysis B: Environmental},
year = {2023},
volume = {339},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.apcatb.2023.123103},
pages = {123103},
doi = {10.1016/j.apcatb.2023.123103}
}