Applied Surface Science, volume 542, pages 148538

Production of V2C MXene using a repetitive pattern of V2AlC MAX phase through microwave heating of Al-V2O5-C system

Ehsan Ghasali ¹

Y. Orooji ¹

Abolfazl Azarniya ²

Masoud Alizadeh ³

Mahmood Kazem Zad ³

Touradjebadzadeh ³

Hide authors affiliations Show authors affiliations: 3 affiliations

College of Materials Science and Engineering, Nanjing Forestry University, No. 159, Longpan Road, Nanjing, 210037, Jiangsu, China |

Department of Materials science and Engineering, Sharif University of Technology, Tehran, Iran |

Ceramic Dept., Materials and Energy Research Center, Alborz, Iran |

Publication type: Journal Article

Publication date: 2021-03-01

Elsevier

Journal: Applied Surface Science

Quartile SCImago

Quartile WOS

Impact factor: 6.7

ISSN: 01694332

DOI: 10.1016/j.apsusc.2020.148538

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Surfaces, Coatings and Films

General Chemistry

General Physics and Astronomy

Condensed Matter Physics

Surfaces and Interfaces

Abstract

The present work focuses on the preparation of V2C MXene from Al-V2O5-C mixture heated in a microwave and etched under HF-based process. In the first stage of process, microwave heating caused the formation of an uncommon periodic pattern of V2AlC-Al2O3 MAX phase. In the second stage of process the aggressive leaching (temperature of 80 °C for 96 h) was performed in HF to remove the interlayer aluminum and Al2O3 particles as impurities. The leaching was not completed at room temperature even after 24 h. XRD and FESEM analyses confirmed the successful formation of V2C MXene and its distorted layer, respectively. HRTEM, XPS and Raman analyses also confirmed a perfect structure of V2C MXene. It seems that the sintering of compacted Al-V2O5-C mixture in microwave and subsequently aggressive leaching of these samples encourage the formation of periodic pattern of MAX phase together with few-layer V2C MXene. Finally, this work led to the successful preparation of MXene using cheap starting materials and the influence of microwave heating on the reduction of V2O5 by Al which could be a driving force for the formation of periodic pattern in V2AlC.

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Ghasali E. et al. Production of V2C MXene using a repetitive pattern of V2AlC MAX phase through microwave heating of Al-V2O5-C system // Applied Surface Science. 2021. Vol. 542. p. 148538.

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Ghasali E., Orooji Y., Azarniya A., Alizadeh M., Kazem Zad M., Touradjebadzadeh Production of V2C MXene using a repetitive pattern of V2AlC MAX phase through microwave heating of Al-V2O5-C system // Applied Surface Science. 2021. Vol. 542. p. 148538.

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RIS Copy

TY - JOUR

DO - 10.1016/j.apsusc.2020.148538

UR - https://doi.org/10.1016/j.apsusc.2020.148538

TI - Production of V2C MXene using a repetitive pattern of V2AlC MAX phase through microwave heating of Al-V2O5-C system

T2 - Applied Surface Science

AU - Ghasali, Ehsan

AU - Orooji, Y.

AU - Azarniya, Abolfazl

AU - Alizadeh, Masoud

AU - Kazem Zad, Mahmood

AU - Touradjebadzadeh

PY - 2021

DA - 2021/03/01 00:00:00

PB - Elsevier

SP - 148538

VL - 542

SN - 0169-4332

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Ghasali,

author = {Ehsan Ghasali and Y. Orooji and Abolfazl Azarniya and Masoud Alizadeh and Mahmood Kazem Zad and Touradjebadzadeh},

title = {Production of V2C MXene using a repetitive pattern of V2AlC MAX phase through microwave heating of Al-V2O5-C system},

journal = {Applied Surface Science},

year = {2021},

volume = {542},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.apsusc.2020.148538},

pages = {148538},

doi = {10.1016/j.apsusc.2020.148538}

}

Found error?

Publisher

Elsevier

Journal

Applied Surface Science

Quartile SCImago

Quartile WOS

Impact factor

6.7

ISSN

01694332 (Print)