Applied Clay Science

, volume 175 , pages 22-29

Eu(III) sorption onto various montmorillonites: Experiments and modeling

Parveen K Verma ^{1, 2}

Anna S Semenkova ³

V. V. Krupskaya ^{4, 5}

Sergey Zakusin ^{4, 5}

Prasanta Raghab Mohapatra ⁶

Anna Romanchuk ³

Stepan N. Kalmykov ³

Hide authors affiliations Show authors affiliations: 6 affiliations

Bhabha Atomic Research Centre, Mumbai 400 085, India |

Homi Bhabha National Institute, 400 094 Mumbai, India |

Lomonosov Moscow State University, 119991, Moscow, Russia. |

⁴

Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Science, 119017 Moscow, Russia |

⁵

Lomonosov Moscow State University, 119991 Moscow, Russia |

⁶

Bhabha Atomic Research Centre, Mumbai - 400 085, India |

Publication type: Journal Article

Publication date: 2019-07-01

Elsevier

Applied Clay Science

scimago Q1

wos Q1

SJR: 1.077

CiteScore: 10.3

Impact factor: 5.8

ISSN: 01691317, 18729053

DOI: 10.1016/J.CLAY.2019.03.001

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Geochemistry and Petrology

Geology

Abstract

Abstract The sorption of Eu(III) onto montmorillonite samples from different deposits such as those of Kutch (India), 10th Khutor deposit (Russia), and Cortijo de Archidona (Spain) was studied over a wide range of experimental conditions by varying the total Eu concentration, pH, and ionic strength. Various bentonite samples showed quantitative sorption at all pH values at low ionic strengths of the solution because of ion exchange interactions. At a higher ionic strength (1 M NaClO4), the sorption is pH-dependent because of the interaction with edge sorption sites and it differed from sample to sample. The difference in the mechanism of interaction at different ionic strengths was confirmed by time-resolved laser-induced fluorescence. Thermodynamic modeling was performed with all experimental data for montmorillonite samples from different sources to create a generalized model for describing their interaction with Eu(III).

Found

1 citation

Mikheev Ivan

PhD in Chemistry

87 publications, 816 citations, 82 reviews

h-index: 17

Lomonosov Moscow State University

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Verma P. K. et al. Eu(III) sorption onto various montmorillonites: Experiments and modeling // Applied Clay Science. 2019. Vol. 175. pp. 22-29.

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Verma P. K., Semenkova A. S., Krupskaya V. V., Zakusin S., Mohapatra P. R., Romanchuk A., Kalmykov S. N. Eu(III) sorption onto various montmorillonites: Experiments and modeling // Applied Clay Science. 2019. Vol. 175. pp. 22-29.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/J.CLAY.2019.03.001

UR - https://linkinghub.elsevier.com/retrieve/pii/S0169131719300651

TI - Eu(III) sorption onto various montmorillonites: Experiments and modeling

T2 - Applied Clay Science

AU - Verma, Parveen K

AU - Semenkova, Anna S

AU - Krupskaya, V. V.

AU - Zakusin, Sergey

AU - Mohapatra, Prasanta Raghab

AU - Romanchuk, Anna

AU - Kalmykov, Stepan N.

PY - 2019

DA - 2019/07/01

PB - Elsevier

SP - 22-29

VL - 175

SN - 0169-1317

SN - 1872-9053

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Verma,

author = {Parveen K Verma and Anna S Semenkova and V. V. Krupskaya and Sergey Zakusin and Prasanta Raghab Mohapatra and Anna Romanchuk and Stepan N. Kalmykov},

title = {Eu(III) sorption onto various montmorillonites: Experiments and modeling},

journal = {Applied Clay Science},

year = {2019},

volume = {175},

publisher = {Elsevier},

month = {jul},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0169131719300651},

pages = {22--29},

doi = {10.1016/J.CLAY.2019.03.001}

}

Publisher

Elsevier

Journal

Applied Clay Science

scimago Q1

wos Q1

SJR

1.077

CiteScore

10.3

Impact factor

5.8

ISSN

01691317 (Print)

18729053

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