Combustion and Flame, volume 122, issue 1-2, pages 165-171
Thermal decomposition of energetic materials 76: chemical pathways that control the burning rates of 5-aminotetrazole and its hydrohalide salts
1
Department of Chemistry & Biochemistry, University of Delaware, Newark, DE 19716 USA
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Publication type: Journal Article
Publication date: 2000-07-01
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Energy Engineering and Power Technology
Fuel Technology
Abstract
The hydrohalide (HCl, HBr, HI) salts of 5-amino-1H-tetrazole (5-ATZ) were flash pyrolyzed under 0.5 MPa of Ar by T-jump/FTIR spectroscopy, and the gaseous products were determined at 350°C, 400°C, and 450°C. Comparison of the products indicated that two global decomposition pathways exist, which give somewhat different products. The first channel is dissociation of the salt to form HX and 5-ATZ followed by decomposition of neutral 5-ATZ. The second channel involves decomposition of the [5-ATZ]+ ion directly. The ratio of these two channels depends on the compound. The first channel is favored over the second channel in the order HCl > HBr > HI, which is the trend of the pKa values of these acids. This information enables both the ordering of the burning rates as a function of pressure as well as the trend in the pressure dependence of the individual burning rates of these compounds to be rationalized.
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Citations by publishers
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1 publication, 1.75%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Brill T. B., Ramanathan H. Thermal decomposition of energetic materials 76: chemical pathways that control the burning rates of 5-aminotetrazole and its hydrohalide salts // Combustion and Flame. 2000. Vol. 122. No. 1-2. pp. 165-171.
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Brill T. B., Ramanathan H. Thermal decomposition of energetic materials 76: chemical pathways that control the burning rates of 5-aminotetrazole and its hydrohalide salts // Combustion and Flame. 2000. Vol. 122. No. 1-2. pp. 165-171.
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TY - JOUR
DO - 10.1016/S0010-2180(00)00111-5
UR - https://doi.org/10.1016/S0010-2180(00)00111-5
TI - Thermal decomposition of energetic materials 76: chemical pathways that control the burning rates of 5-aminotetrazole and its hydrohalide salts
T2 - Combustion and Flame
AU - Brill, T. B.
AU - Ramanathan, H.
PY - 2000
DA - 2000/07/01 00:00:00
PB - Elsevier
SP - 165-171
IS - 1-2
VL - 122
SN - 0010-2180
ER -
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@article{2000_Brill,
author = {T. B. Brill and H. Ramanathan},
title = {Thermal decomposition of energetic materials 76: chemical pathways that control the burning rates of 5-aminotetrazole and its hydrohalide salts},
journal = {Combustion and Flame},
year = {2000},
volume = {122},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/S0010-2180(00)00111-5},
number = {1-2},
pages = {165--171},
doi = {10.1016/S0010-2180(00)00111-5}
}
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Brill, T. B., and H. Ramanathan. “Thermal decomposition of energetic materials 76: chemical pathways that control the burning rates of 5-aminotetrazole and its hydrohalide salts.” Combustion and Flame, vol. 122, no. 1-2, Jul. 2000, pp. 165-171. https://doi.org/10.1016/S0010-2180(00)00111-5.