New potentially cytotoxic thiolatogold(I) complexes of 1,1′-bis(diphenylphosphino) ferrocene
Publication type: Journal Article
Publication date: 1996-12-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract 1,1′-Bis[chlorogold(I) diphenylphosphino] ferrocene (1) was chosen as the starting material to synthesize new thiolato gold(I) complexes. This has been achieved by substituting the chlorine atoms by monofunctional and bifunctional thiolates affording ‘open’ thiolatogold complexes and trimetallic ferrocenophane-type structures, respectively. The new 1,1′-bis(2,6-dithia-1-phosphanyl)ferrocene (7) containing directly linked P and S atoms was also prepared but no gold complex was obtained. Compound 2 crystallizes in the monoclinic space group P21/n with a=10.2632), b=21.064(4), c=16.259(3) A , β=97.06(2)° and V=3.488(1) A 3 . The distance between the two gold atoms (3.06 A) indicates a significant contact interaction. Compounds 2–5 have allowed antitumoral efficiency on human bladder and colon carcinoma.
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GOST
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Viotte M. et al. New potentially cytotoxic thiolatogold(I) complexes of 1,1′-bis(diphenylphosphino) ferrocene // Inorganica Chimica Acta. 1996. Vol. 253. No. 1. pp. 71-76.
GOST all authors (up to 50)
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Viotte M., Gautheron B., Nifant'ev I. E., Kuz'mina L. G. New potentially cytotoxic thiolatogold(I) complexes of 1,1′-bis(diphenylphosphino) ferrocene // Inorganica Chimica Acta. 1996. Vol. 253. No. 1. pp. 71-76.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0020-1693(96)05111-0
UR - https://linkinghub.elsevier.com/retrieve/pii/S0020169396051110
TI - New potentially cytotoxic thiolatogold(I) complexes of 1,1′-bis(diphenylphosphino) ferrocene
T2 - Inorganica Chimica Acta
AU - Viotte, M.
AU - Gautheron, B.
AU - Nifant'ev, Ilya E.
AU - Kuz'mina, L. G.
PY - 1996
DA - 1996/12/01
PB - Elsevier
SP - 71-76
IS - 1
VL - 253
SN - 0020-1693
SN - 1873-3255
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1996_Viotte,
author = {M. Viotte and B. Gautheron and Ilya E. Nifant'ev and L. G. Kuz'mina},
title = {New potentially cytotoxic thiolatogold(I) complexes of 1,1′-bis(diphenylphosphino) ferrocene},
journal = {Inorganica Chimica Acta},
year = {1996},
volume = {253},
publisher = {Elsevier},
month = {dec},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0020169396051110},
number = {1},
pages = {71--76},
doi = {10.1016/S0020-1693(96)05111-0}
}
Cite this
MLA
Copy
Viotte, M., et al. “New potentially cytotoxic thiolatogold(I) complexes of 1,1′-bis(diphenylphosphino) ferrocene.” Inorganica Chimica Acta, vol. 253, no. 1, Dec. 1996, pp. 71-76. https://linkinghub.elsevier.com/retrieve/pii/S0020169396051110.
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