Inorganica Chimica Acta, volume 141, issue 2, pages 263-274
1H, 13C and 199Hg NMR characteristics of new amine-mercuric chloride complexes
Publication type: Journal Article
Publication date: 1988-01-01
Journal:
Inorganica Chimica Acta
Q2
Q2
SJR: 0.386
CiteScore: 6.0
Impact factor: 2.7
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Reduction of some N-alkylimines has been achieved with NaBH4 to give the corresponding secondary amines with high yields (85–95%). These amines were characterized on the bases of their 1H and 13C NMR spectra. The reaction of these amines with mercuric chloride to afford the corresponding complexes was found to occur through a weak dative bond between the nitrogen lone pair of electrons and the mercury atom to form HgCl2L2 complexes. The 1H, 13C and 199Hg NMR chemical shifts have been obtained as well as 1J(13CH) and 2J(13CH) coupling constants. Labelling with nitrogen-15 revealed that there is a weak coupling between the nitrogen and the 199Hg.
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Al Showiman S. S. 1H, 13C and 199Hg NMR characteristics of new amine-mercuric chloride complexes // Inorganica Chimica Acta. 1988. Vol. 141. No. 2. pp. 263-274.
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Al Showiman S. S. 1H, 13C and 199Hg NMR characteristics of new amine-mercuric chloride complexes // Inorganica Chimica Acta. 1988. Vol. 141. No. 2. pp. 263-274.
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RIS
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TY - JOUR
DO - 10.1016/s0020-1693(00)83918-3
UR - https://doi.org/10.1016/s0020-1693(00)83918-3
TI - 1H, 13C and 199Hg NMR characteristics of new amine-mercuric chloride complexes
T2 - Inorganica Chimica Acta
AU - Al Showiman, Salim S
PY - 1988
DA - 1988/01/01
PB - Elsevier
SP - 263-274
IS - 2
VL - 141
SN - 0020-1693
SN - 1873-3255
ER -
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BibTex (up to 50 authors)
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@article{1988_Al Showiman,
author = {Salim S Al Showiman},
title = {1H, 13C and 199Hg NMR characteristics of new amine-mercuric chloride complexes},
journal = {Inorganica Chimica Acta},
year = {1988},
volume = {141},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/s0020-1693(00)83918-3},
number = {2},
pages = {263--274},
doi = {10.1016/s0020-1693(00)83918-3}
}
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MLA
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Al Showiman, Salim S.. “1H, 13C and 199Hg NMR characteristics of new amine-mercuric chloride complexes.” Inorganica Chimica Acta, vol. 141, no. 2, Jan. 1988, pp. 263-274. https://doi.org/10.1016/s0020-1693(00)83918-3.