Reactivity of cyclopallatated compounds. III. Reaction with group V donor atoms ligands
1
Laboratoire de Chimie de Coordination du LA 134, Université Louis Pasteur, 4 rue Blaise Pascal, 67008 Strasbourg, France
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Publication type: Journal Article
Publication date: 1975-01-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract In organic solvents, ligands such as pyridine, trialkyl and triarylphosphines, Triphenylarsine and stibine react quantitatively with cyclopalladated dimers of the type (Pd(CN)X) 2 (where CN = acetophenone hydazone) to give monomeric compounds of the type Pd(C-N)LX(X = Cl, Br, I). The presence of an excess of phosphine leads to Pd(C-N)L 2 X, in which the nitrogen is no longer coordinated. With bidentate ligands a new type of complexes is obtained: in which AA represents 1,2-bis(diphenylphosphino)ethane and 1,2-bis(diphenylarsino)ethane. With ethylenediamine (en), only the ionic complex [Pd(CN) en] + X − is formed. In aqueous solutions, cationic compounds of palladium can be isolated with pyridine or bidentate ligands. The stereochemistry of these complexes is discussed on the basis of v(PdX) infrared frequencies; N.M.R. data for the CN ligand are given.
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Citations from 2024:
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Dehand J., PFEFFER M. A., Zinsius M. Reactivity of cyclopallatated compounds. III. Reaction with group V donor atoms ligands // Inorganica Chimica Acta. 1975. Vol. 13. pp. 229-232.
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Dehand J., PFEFFER M. A., Zinsius M. Reactivity of cyclopallatated compounds. III. Reaction with group V donor atoms ligands // Inorganica Chimica Acta. 1975. Vol. 13. pp. 229-232.
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TY - JOUR
DO - 10.1016/S0020-1693(00)90202-0
UR - https://doi.org/10.1016/S0020-1693(00)90202-0
TI - Reactivity of cyclopallatated compounds. III. Reaction with group V donor atoms ligands
T2 - Inorganica Chimica Acta
AU - Dehand, J
AU - PFEFFER, Marc A
AU - Zinsius, M
PY - 1975
DA - 1975/01/01
PB - Elsevier
SP - 229-232
VL - 13
SN - 0020-1693
SN - 1873-3255
ER -
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BibTex (up to 50 authors)
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@article{1975_Dehand,
author = {J Dehand and Marc A PFEFFER and M Zinsius},
title = {Reactivity of cyclopallatated compounds. III. Reaction with group V donor atoms ligands},
journal = {Inorganica Chimica Acta},
year = {1975},
volume = {13},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0020-1693(00)90202-0},
pages = {229--232},
doi = {10.1016/S0020-1693(00)90202-0}
}