The influence of real structure of gold catalysts in the partial hydrogenation of acrolein
Тип публикации: Journal Article
Дата публикации: 2003-01-01
scimago Q1
wos Q1
БС1
SJR: 1.558
CiteScore: 10.9
Impact factor: 6.5
ISSN: 00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Краткое описание
The hydrogenation of acrolein on supported gold catalysts has been used as test reaction to study several aspects of structure sensitivity, i.e., the dependence of activity and selectivity on the size of gold particles. We focused our work on the influence of the geometrical configuration of the supported gold nanoparticles , namely the occurrence of multiply twinned particles (MTPs) and the degree of rounding. A higher number of MTPs resulted in a lowering of selectivity to the desired product, allyl alcohol, as well as a lowering of the turnover frequency. The higher amount frequency of a gold catalyst supported on TiO 2 compared to ZrO 2 is attributed to a higher degree of rounding of the former.
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Mohr C. H., Hofmeister H., Claus P. The influence of real structure of gold catalysts in the partial hydrogenation of acrolein // Journal of Catalysis. 2003. Vol. 213. No. 1. pp. 86-94.
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Mohr C. H., Hofmeister H., Claus P. The influence of real structure of gold catalysts in the partial hydrogenation of acrolein // Journal of Catalysis. 2003. Vol. 213. No. 1. pp. 86-94.
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TY - JOUR
DO - 10.1016/S0021-9517(02)00043-X
UR - https://doi.org/10.1016/S0021-9517(02)00043-X
TI - The influence of real structure of gold catalysts in the partial hydrogenation of acrolein
T2 - Journal of Catalysis
AU - Mohr, Christian H.
AU - Hofmeister, H.
AU - Claus, P
PY - 2003
DA - 2003/01/01
PB - Elsevier
SP - 86-94
IS - 1
VL - 213
SN - 0021-9517
SN - 1090-2694
ER -
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@article{2003_Mohr,
author = {Christian H. Mohr and H. Hofmeister and P Claus},
title = {The influence of real structure of gold catalysts in the partial hydrogenation of acrolein},
journal = {Journal of Catalysis},
year = {2003},
volume = {213},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0021-9517(02)00043-X},
number = {1},
pages = {86--94},
doi = {10.1016/S0021-9517(02)00043-X}
}
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MLA
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Mohr, Christian H., et al. “The influence of real structure of gold catalysts in the partial hydrogenation of acrolein.” Journal of Catalysis, vol. 213, no. 1, Jan. 2003, pp. 86-94. https://doi.org/10.1016/S0021-9517(02)00043-X.