Journal of Electroanalytical Chemistry, volume 473, issue 1-2, pages 192-203

A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy

D J Fermín
David Fermin 1
E. A. Ponomarev
E. A. Ponomarev 1
L. M. Peter
Laurence Peter 1
1
 
Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, (UK)
Publication typeJournal Article
Publication date1999-09-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.5
ISSN15726657
General Chemical Engineering
Analytical Chemistry
Electrochemistry
Abstract
The steady state and dynamic photoelectrochemical behaviour of single crystal cadmium sulfide in non-stabilising electrolytes has been compared with the response of the same electrode in the hole scavenging electrolyte Na 2 SO 3 . The kinetics of the elementary steps involved in photo-dissolution have been investigated by intensity modulated photocurrent spectroscopy (IMPS) and photoelectrochemical impedance spectroscopy (PEIS). The theoretical PEIS responses for a two hole transfer process have been derived and related to the corresponding theoretical IMPS responses. PEIS and IMPS data as well as the steady state photocurrent characteristics have been analysed within the framework of a model involving hole capture to form a surface bound intermediate species. The effects of the accumulation of this species on the steady state and dynamic response of the electrode are discussed.

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Fermín D. J. et al. A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy // Journal of Electroanalytical Chemistry. 1999. Vol. 473. No. 1-2. pp. 192-203.
GOST all authors (up to 50) Copy
Fermín D. J., Fermin D., Ponomarev E. A., Ponomarev E. A., Peter L. M., Peter L. A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy // Journal of Electroanalytical Chemistry. 1999. Vol. 473. No. 1-2. pp. 192-203.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/S0022-0728(99)00109-6
UR - https://doi.org/10.1016/S0022-0728(99)00109-6
TI - A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy
T2 - Journal of Electroanalytical Chemistry
AU - Fermín, D J
AU - Ponomarev, E. A.
AU - Peter, L. M.
AU - Fermin, David
AU - Ponomarev, E. A.
AU - Peter, Laurence
PY - 1999
DA - 1999/09/01 00:00:00
PB - Elsevier
SP - 192-203
IS - 1-2
VL - 473
SN - 1572-6657
ER -
BibTex |
Cite this
BibTex Copy
@article{1999_Fermín,
author = {D J Fermín and E. A. Ponomarev and L. M. Peter and David Fermin and E. A. Ponomarev and Laurence Peter},
title = {A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy},
journal = {Journal of Electroanalytical Chemistry},
year = {1999},
volume = {473},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0022-0728(99)00109-6},
number = {1-2},
pages = {192--203},
doi = {10.1016/S0022-0728(99)00109-6}
}
MLA
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MLA Copy
Fermín, D. J., et al. “A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy.” Journal of Electroanalytical Chemistry, vol. 473, no. 1-2, Sep. 1999, pp. 192-203. https://doi.org/10.1016/S0022-0728(99)00109-6.
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