A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy
Publication type: Journal Article
Publication date: 1999-09-01
scimago Q1
wos Q1
SJR: 0.760
CiteScore: 8.1
Impact factor: 4.1
ISSN: 15726657, 18732569
General Chemical Engineering
Analytical Chemistry
Electrochemistry
Abstract
The steady state and dynamic photoelectrochemical behaviour of single crystal cadmium sulfide in non-stabilising electrolytes has been compared with the response of the same electrode in the hole scavenging electrolyte Na 2 SO 3 . The kinetics of the elementary steps involved in photo-dissolution have been investigated by intensity modulated photocurrent spectroscopy (IMPS) and photoelectrochemical impedance spectroscopy (PEIS). The theoretical PEIS responses for a two hole transfer process have been derived and related to the corresponding theoretical IMPS responses. PEIS and IMPS data as well as the steady state photocurrent characteristics have been analysed within the framework of a model involving hole capture to form a surface bound intermediate species. The effects of the accumulation of this species on the steady state and dynamic response of the electrode are discussed.
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140
Total citations:
140
Citations from 2024:
18
(12.86%)
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GOST
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Fermín D. J. et al. A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy // Journal of Electroanalytical Chemistry. 1999. Vol. 473. No. 1-2. pp. 192-203.
GOST all authors (up to 50)
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Fermin D., Ponomarev E. A., Peter L. A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy // Journal of Electroanalytical Chemistry. 1999. Vol. 473. No. 1-2. pp. 192-203.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0022-0728(99)00109-6
UR - https://doi.org/10.1016/S0022-0728(99)00109-6
TI - A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy
T2 - Journal of Electroanalytical Chemistry
AU - Fermin, David
AU - Ponomarev, E. A.
AU - Peter, Laurence
PY - 1999
DA - 1999/09/01
PB - Elsevier
SP - 192-203
IS - 1-2
VL - 473
SN - 1572-6657
SN - 1873-2569
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Fermín,
author = {David Fermin and E. A. Ponomarev and Laurence Peter},
title = {A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy},
journal = {Journal of Electroanalytical Chemistry},
year = {1999},
volume = {473},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0022-0728(99)00109-6},
number = {1-2},
pages = {192--203},
doi = {10.1016/S0022-0728(99)00109-6}
}
Cite this
MLA
Copy
Fermín, D. J., et al. “A kinetic study of CdS photocorrosion by intensity modulated photocurrent and photoelectrochemical impedance spectroscopy.” Journal of Electroanalytical Chemistry, vol. 473, no. 1-2, Sep. 1999, pp. 192-203. https://doi.org/10.1016/S0022-0728(99)00109-6.