Syntheses of lipophilic tetraarylborate ions substituted with many perfluoroalkyl groups and their stability under acid conditions
Publication type: Journal Article
Publication date: 2000-03-01
scimago Q3
wos Q3
SJR: 0.333
CiteScore: 3.7
Impact factor: 1.9
ISSN: 00221139, 18733328
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Abstract
Syntheses are investigated on several new kinds of perfluoroalkyl-substituted tetraarylborate ions such as tetrakis(3,5-bis(nonafluorobutyl)phenyl)borate, tetrakis(3,5-bis(heptafluoro-2-propyl)phenyl)borate ( PFPB ), tetrakis(3-(heptafluoro-2-propyl)-1-(trifluoromethyl)phenyl)borate, and tetrakis(3-(heptafluoro-2-propyl)phenyl)borate. Solubilities of tetramethylammonium tetraarylborates in some hydrophobic halocarbon solvents and rate constants of acid-catalyzed decomposition of the tetraarylborate ions in methanolic sulfuric acid solutions and in dichloromethane/aqueous sulfuric acid two-phase system are determined. Trifluoromethyl- and perfluoroalkyl-substituent effects on the lipophilicity and chemical stability of the tetraarylborate ions are discussed in comparisons with a range of those described previously.
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16
Total citations:
16
Citations from 2025:
3
(18.75%)
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MLA
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GOST
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Fujiki K. et al. Syntheses of lipophilic tetraarylborate ions substituted with many perfluoroalkyl groups and their stability under acid conditions // Journal of Fluorine Chemistry. 2000. Vol. 102. No. 1-2. pp. 293-300.
GOST all authors (up to 50)
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Fujiki K., Ichikawa J., Kobayashi H., Sonoda A., SONODA T. Syntheses of lipophilic tetraarylborate ions substituted with many perfluoroalkyl groups and their stability under acid conditions // Journal of Fluorine Chemistry. 2000. Vol. 102. No. 1-2. pp. 293-300.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0022-1139(99)00291-2
UR - https://doi.org/10.1016/S0022-1139(99)00291-2
TI - Syntheses of lipophilic tetraarylborate ions substituted with many perfluoroalkyl groups and their stability under acid conditions
T2 - Journal of Fluorine Chemistry
AU - Fujiki, Kanji
AU - Ichikawa, J.
AU - Kobayashi, Hiroshi
AU - Sonoda, Akinari
AU - SONODA, Takaaki
PY - 2000
DA - 2000/03/01
PB - Elsevier
SP - 293-300
IS - 1-2
VL - 102
SN - 0022-1139
SN - 1873-3328
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2000_Fujiki,
author = {Kanji Fujiki and J. Ichikawa and Hiroshi Kobayashi and Akinari Sonoda and Takaaki SONODA},
title = {Syntheses of lipophilic tetraarylborate ions substituted with many perfluoroalkyl groups and their stability under acid conditions},
journal = {Journal of Fluorine Chemistry},
year = {2000},
volume = {102},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/S0022-1139(99)00291-2},
number = {1-2},
pages = {293--300},
doi = {10.1016/S0022-1139(99)00291-2}
}
Cite this
MLA
Copy
Fujiki, Kanji, et al. “Syntheses of lipophilic tetraarylborate ions substituted with many perfluoroalkyl groups and their stability under acid conditions.” Journal of Fluorine Chemistry, vol. 102, no. 1-2, Mar. 2000, pp. 293-300. https://doi.org/10.1016/S0022-1139(99)00291-2.