Solvent induced temperature dependencies of NMR parameters of hydrogen bonded anionic clusters
Publication type: Journal Article
Publication date: 2004-07-01
scimago Q2
wos Q2
SJR: 0.628
CiteScore: 8.0
Impact factor: 4.7
ISSN: 00222860, 18728014
Organic Chemistry
Inorganic Chemistry
Spectroscopy
Analytical Chemistry
Abstract
The solvent induced temperature dependence of NMR parameters (proton and fluorine chemical shifts, the two-bond scalar spin coupling constant across the hydrogen bridge, 2h J FF ) for dihydrogen trifluoride anion, (FH) 2 F − , in a polar aprotic solvent, CDF 3 /CDF 2 Cl, is reported and discussed. The results are interpreted in terms of a simple electrostatic model, accounting a decrease of electrostatic repulsion of two negatively charged fluorine atoms on placing into a dielectric medium. The conclusion is drawn that polar medium causes some contraction of hydrogen bonds in ionic clusters combined with a decrease of hydrogen bond asymmetry.
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GOST
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Golubev N. S. et al. Solvent induced temperature dependencies of NMR parameters of hydrogen bonded anionic clusters // Journal of Molecular Structure. 2004. Vol. 697. No. 1-3. pp. 9-15.
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Golubev N. S., Shenderovich I. G., Shchepkin D. N., Tolstoy P. M. Solvent induced temperature dependencies of NMR parameters of hydrogen bonded anionic clusters // Journal of Molecular Structure. 2004. Vol. 697. No. 1-3. pp. 9-15.
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RIS
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TY - JOUR
DO - 10.1016/S0022-2860(03)00423-X
UR - https://doi.org/10.1016/S0022-2860(03)00423-X
TI - Solvent induced temperature dependencies of NMR parameters of hydrogen bonded anionic clusters
T2 - Journal of Molecular Structure
AU - Golubev, Nikolai S.
AU - Shenderovich, Ilja G.
AU - Shchepkin, Dmitry N.
AU - Tolstoy, Peter M.
PY - 2004
DA - 2004/07/01
PB - Elsevier
SP - 9-15
IS - 1-3
VL - 697
SN - 0022-2860
SN - 1872-8014
ER -
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BibTex (up to 50 authors)
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@article{2004_Golubev,
author = {Nikolai S. Golubev and Ilja G. Shenderovich and Dmitry N. Shchepkin and Peter M. Tolstoy},
title = {Solvent induced temperature dependencies of NMR parameters of hydrogen bonded anionic clusters},
journal = {Journal of Molecular Structure},
year = {2004},
volume = {697},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/S0022-2860(03)00423-X},
number = {1-3},
pages = {9--15},
doi = {10.1016/S0022-2860(03)00423-X}
}
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MLA
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Golubev, Nikolai S., et al. “Solvent induced temperature dependencies of NMR parameters of hydrogen bonded anionic clusters.” Journal of Molecular Structure, vol. 697, no. 1-3, Jul. 2004, pp. 9-15. https://doi.org/10.1016/S0022-2860(03)00423-X.
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