Diamagnetic and paramagnetic binuclear cyclopentadienyl-fulvalene-nitrene complexes of niobium: Synthesis, spectra and structure
1
Laboratory of Organo - Element Compounds, Chemistry Department, University of Moscow, Moscow B234 U.S.S.R.
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Publication type: Journal Article
Publication date: 1982-03-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Oxidation of the diamagnetic binuclear niobium complexes (η 5 :η 5 -C 5 H 4 C 5 H 4 )-(C 5 H 5 ) 2 Nb 2 (μ-NC 6 H 4 R) 2 (R = H and OCH 3 ) (I) yields stable paramagnetic cations [η 5 :η 5 -C 5 H 4 C 5 H 4 C 5 H 4 ) (C 5 H 5 ) 2 Nb 2 (η-NC 6 H 4 R) 2 ] + (II). IR, EPR, and UV spectra of I and II have been studied. The crystal and molecular structures of I and II with R = OCH 3 have been determined and compared.
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Lemenovskii D. A. et al. Diamagnetic and paramagnetic binuclear cyclopentadienyl-fulvalene-nitrene complexes of niobium: Synthesis, spectra and structure // Journal of Organometallic Chemistry. 1982. Vol. 228. No. 2. pp. 153-170.
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Lemenovskii D. A., Fedin V. P., Slovohotov Yu. L., Struchkov Y. T. Diamagnetic and paramagnetic binuclear cyclopentadienyl-fulvalene-nitrene complexes of niobium: Synthesis, spectra and structure // Journal of Organometallic Chemistry. 1982. Vol. 228. No. 2. pp. 153-170.
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TY - JOUR
DO - 10.1016/S0022-328X(00)87094-1
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X00870941
TI - Diamagnetic and paramagnetic binuclear cyclopentadienyl-fulvalene-nitrene complexes of niobium: Synthesis, spectra and structure
T2 - Journal of Organometallic Chemistry
AU - Lemenovskii, D A
AU - Fedin, Vladimir P.
AU - Slovohotov, Yu L
AU - Struchkov, Yu. T.
PY - 1982
DA - 1982/03/01
PB - Elsevier
SP - 153-170
IS - 2
VL - 228
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{1982_Lemenovskii,
author = {D A Lemenovskii and Vladimir P. Fedin and Yu L Slovohotov and Yu. T. Struchkov},
title = {Diamagnetic and paramagnetic binuclear cyclopentadienyl-fulvalene-nitrene complexes of niobium: Synthesis, spectra and structure},
journal = {Journal of Organometallic Chemistry},
year = {1982},
volume = {228},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X00870941},
number = {2},
pages = {153--170},
doi = {10.1016/S0022-328X(00)87094-1}
}
Cite this
MLA
Copy
Lemenovskii, D. A., et al. “Diamagnetic and paramagnetic binuclear cyclopentadienyl-fulvalene-nitrene complexes of niobium: Synthesis, spectra and structure.” Journal of Organometallic Chemistry, vol. 228, no. 2, Mar. 1982, pp. 153-170. https://linkinghub.elsevier.com/retrieve/pii/S0022328X00870941.