Pyridinylimine-based nickel(II) and palladium(II) complexes: preparation, structural characterization and use as alkene polymerization catalysts
Publication type: Journal Article
Publication date: 2000-07-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Preparation of four dimeric nickel(II) complexes and three monomeric palladium(II) complexes bearing didentate pyridinylimine ligands is described. The solid-state structures of these compounds have been determined by single-crystal X-ray diffraction. After activation with methylaluminoxane (MAO) the nickel compounds were used as catalysts in ethylene polymerization producing nearly linear or primarily methyl-branched polymers. The effect of ligand environment was most evident on degree of branching, while catalytic activity and molecular weight of the polymer were more dependent on the general catalyst composition as well as reaction conditions. Activation of the dichloropalladium(II) complexes with MAO yields highly active catalysts for the polymerization of bicyclo[2.2.1]hept-2-ene (norbornene) whereas only low conversions (
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234
Total citations:
234
Citations from 2025:
7
(2.99%)
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GOST
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Laine T. V. et al. Pyridinylimine-based nickel(II) and palladium(II) complexes: preparation, structural characterization and use as alkene polymerization catalysts // Journal of Organometallic Chemistry. 2000. Vol. 606. No. 2. pp. 112-124.
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Laine T. V., Piironen U., Lappalainen K., Klinga M., Aitola E., Leskelä M. Pyridinylimine-based nickel(II) and palladium(II) complexes: preparation, structural characterization and use as alkene polymerization catalysts // Journal of Organometallic Chemistry. 2000. Vol. 606. No. 2. pp. 112-124.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0022-328X(00)00291-6
UR - https://doi.org/10.1016/S0022-328X(00)00291-6
TI - Pyridinylimine-based nickel(II) and palladium(II) complexes: preparation, structural characterization and use as alkene polymerization catalysts
T2 - Journal of Organometallic Chemistry
AU - Laine, Timo V
AU - Piironen, Ulla
AU - Lappalainen, Kristian
AU - Klinga, Martti
AU - Aitola, Erkki
AU - Leskelä, Markku
PY - 2000
DA - 2000/07/01
PB - Elsevier
SP - 112-124
IS - 2
VL - 606
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{2000_Laine,
author = {Timo V Laine and Ulla Piironen and Kristian Lappalainen and Martti Klinga and Erkki Aitola and Markku Leskelä},
title = {Pyridinylimine-based nickel(II) and palladium(II) complexes: preparation, structural characterization and use as alkene polymerization catalysts},
journal = {Journal of Organometallic Chemistry},
year = {2000},
volume = {606},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/S0022-328X(00)00291-6},
number = {2},
pages = {112--124},
doi = {10.1016/S0022-328X(00)00291-6}
}
Cite this
MLA
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Laine, Timo V., et al. “Pyridinylimine-based nickel(II) and palladium(II) complexes: preparation, structural characterization and use as alkene polymerization catalysts.” Journal of Organometallic Chemistry, vol. 606, no. 2, Jul. 2000, pp. 112-124. https://doi.org/10.1016/S0022-328X(00)00291-6.