Reactions of coordinated molecules XI. The reaction of the rhenium tetracarbonyl metallo-acetylacetone complex with hydrazines
Тип публикации: Journal Article
Дата публикации: 1977-11-01
scimago Q3
wos Q2
БС2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The reaction of the rhenium tetracarbonyl metallo-acetylacetone molecule, cis -(OC) 4 Re[C(CH 3 )O⋰H⋰O(CH 3 )C], with hydrazine, methylhydrazine and phenylhydrazine affords the corresponding acetyl-amine complexes, cis -(OC) 4 - Re(COCH 3 )(NH 2 R), where R = H, CH 3 , or C 6 H 5 , and acetonitrile. The reactions were followed by proton NMR at 36°C. The half-lilfe of the reaction with phenylhydrazine was 8.67 minutes while the other two hydrazines gave complete reaction within 30 seconds. The X-ray molecular structure determination of the acetyl-aniline complex is reported.
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Lukehart C. M., Zeile J. V. Reactions of coordinated molecules XI. The reaction of the rhenium tetracarbonyl metallo-acetylacetone complex with hydrazines // Journal of Organometallic Chemistry. 1977. Vol. 140. No. 3. pp. 309-316.
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Lukehart C. M., Zeile J. V. Reactions of coordinated molecules XI. The reaction of the rhenium tetracarbonyl metallo-acetylacetone complex with hydrazines // Journal of Organometallic Chemistry. 1977. Vol. 140. No. 3. pp. 309-316.
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TY - JOUR
DO - 10.1016/s0022-328x(00)89351-1
UR - https://doi.org/10.1016/s0022-328x(00)89351-1
TI - Reactions of coordinated molecules XI. The reaction of the rhenium tetracarbonyl metallo-acetylacetone complex with hydrazines
T2 - Journal of Organometallic Chemistry
AU - Lukehart, C. M
AU - Zeile, Jane V
PY - 1977
DA - 1977/11/01
PB - Elsevier
SP - 309-316
IS - 3
VL - 140
SN - 0022-328X
SN - 1872-8561
ER -
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@article{1977_Lukehart,
author = {C. M Lukehart and Jane V Zeile},
title = {Reactions of coordinated molecules XI. The reaction of the rhenium tetracarbonyl metallo-acetylacetone complex with hydrazines},
journal = {Journal of Organometallic Chemistry},
year = {1977},
volume = {140},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/s0022-328x(00)89351-1},
number = {3},
pages = {309--316},
doi = {10.1016/s0022-328x(00)89351-1}
}
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Lukehart, C. M., and Jane V Zeile. “Reactions of coordinated molecules XI. The reaction of the rhenium tetracarbonyl metallo-acetylacetone complex with hydrazines.” Journal of Organometallic Chemistry, vol. 140, no. 3, Nov. 1977, pp. 309-316. https://doi.org/10.1016/s0022-328x(00)89351-1.