Elsevier
Journal of Organometallic Chemistry
,  том 246 ,  издание 1 ,  страницы 19-27

Organoboron compounds

Тип публикации: Journal Article
Дата публикации: 1983-04-01
Elsevier
SCImago Q3
WOS Q2
БС2
SJR: 0.374
CiteScore: 4.3
Impact factor: 2.7
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The complex of 1-boraadamantane with tetrahydrofuran (I) reacts with iodine in the presence of lithium methylate or methyllithium to produce 3-methoxy- (III) and 3-methyl-7-iodomethyl-3-borabicyclo[3.3.1]nonane (X), respectively. Further iodination of III in the presence of lithium methylate proceeds in a complicated manner due to replacement of iodine by the methoxy group in the starting compound. The high reactivity of the halogen in III permitted a one-pot synthesis of 3-methoxy-7-methoxymethyl-3-borabicyclo[3.3.1]nonane from I. Iodination of lithium 1-isopropenyl-1-boraadamantanate leads, after methanolysis, to 3-methoxy-7-isobutenyl-3-borabicyclo[3.3.1]nonane. The latter compound was converted to 7-isobutenyl-3-methyl-3-borabicyclo[3.3.1]nonane on treatment with MeMgI.
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ГОСТ |
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ГОСТ Скопировать
Mikhailov B. M., Gurskii M. E., Pershin D. G. Organoboron compounds // Journal of Organometallic Chemistry. 1983. Vol. 246. No. 1. pp. 19-27.
ГОСТ со всеми авторами (до 50) Скопировать
Mikhailov B. M., Gurskii M. E., Pershin D. G. Organoboron compounds // Journal of Organometallic Chemistry. 1983. Vol. 246. No. 1. pp. 19-27.
RIS |
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RIS Скопировать
TY - JOUR
DO - 10.1016/s0022-328x(00)98647-9
UR - https://doi.org/10.1016/s0022-328x(00)98647-9
TI - Organoboron compounds
T2 - Journal of Organometallic Chemistry
AU - Mikhailov, B M
AU - Gurskii, M E
AU - Pershin, D G
PY - 1983
DA - 1983/04/01
PB - Elsevier
SP - 19-27
IS - 1
VL - 246
SN - 0022-328X
SN - 1872-8561
ER -
BibTex |
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@article{1983_Mikhailov,
author = {B M Mikhailov and M E Gurskii and D G Pershin},
title = {Organoboron compounds},
journal = {Journal of Organometallic Chemistry},
year = {1983},
volume = {246},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/s0022-328x(00)98647-9},
number = {1},
pages = {19--27},
doi = {10.1016/s0022-328x(00)98647-9}
}
MLA
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MLA Скопировать
Mikhailov, B. M., et al. “Organoboron compounds.” Journal of Organometallic Chemistry, vol. 246, no. 1, Apr. 1983, pp. 19-27. https://doi.org/10.1016/s0022-328x(00)98647-9.
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