Concerning the transannular bond in silatranes and germatranes: a quantum chemical study
Publication type: Journal Article
Publication date: 1999-04-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
For a series of silatranes and germatranes the structure of isolated molecules was investigated by the quantum chemistry molecular orbital method. The transannular bond N→M lengthens with the strengthening of a substituent +I-effect, however, in the solid state the bond length depends considerably on the crystal field effects. Due to the latter, this transannular bond in crystals is shorter than that in isolated molecules.
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47
Total citations:
47
Citations from 2025:
2
(4.26%)
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MLA
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GOST
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Belyakov S., Ignatovich L., Lukevics E. Concerning the transannular bond in silatranes and germatranes: a quantum chemical study // Journal of Organometallic Chemistry. 1999. Vol. 577. No. 2. pp. 205-210.
GOST all authors (up to 50)
Copy
Belyakov S., Ignatovich L., Lukevics E. Concerning the transannular bond in silatranes and germatranes: a quantum chemical study // Journal of Organometallic Chemistry. 1999. Vol. 577. No. 2. pp. 205-210.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0022-328X(98)01041-9
UR - https://doi.org/10.1016/S0022-328X(98)01041-9
TI - Concerning the transannular bond in silatranes and germatranes: a quantum chemical study
T2 - Journal of Organometallic Chemistry
AU - Belyakov, S.
AU - Ignatovich, L.
AU - Lukevics, E.
PY - 1999
DA - 1999/04/01
PB - Elsevier
SP - 205-210
IS - 2
VL - 577
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Belyakov,
author = {S. Belyakov and L. Ignatovich and E. Lukevics},
title = {Concerning the transannular bond in silatranes and germatranes: a quantum chemical study},
journal = {Journal of Organometallic Chemistry},
year = {1999},
volume = {577},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/S0022-328X(98)01041-9},
number = {2},
pages = {205--210},
doi = {10.1016/S0022-328X(98)01041-9}
}
Cite this
MLA
Copy
Belyakov, S., et al. “Concerning the transannular bond in silatranes and germatranes: a quantum chemical study.” Journal of Organometallic Chemistry, vol. 577, no. 2, Apr. 1999, pp. 205-210. https://doi.org/10.1016/S0022-328X(98)01041-9.