Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride
P. Prem Kiran
1
,
N. K. M. NAGA SRINIVAS
1
,
D Raghunath Reddy
2
,
BHASKAR G. MAIYA
2
,
Aditya Dharmadhikari
3
,
Arvinder S. Sandhu
3
,
G. Gnana Kumar
3
,
D. Narayana Rao
1
Publication type: Journal Article
Publication date: 2002-02-01
scimago Q2
wos Q2
SJR: 0.526
CiteScore: 4.8
Impact factor: 2.5
ISSN: 00304018, 18730310
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
Electrical and Electronic Engineering
Abstract
Optical limiting performance and third-order nonlinearity χ (3) are investigated in 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride ([(TTP)P V Cl 2 ] + ). Heavy atom effect exerted by the two axial chlorides is found to result in low fluorescence yield (∅ fl ), shorter lifetimes of S 1 ,T 1 and faster intersystem crossing (ISC), leading to larger excited state absorption (ESA) from T 1 →T n . This phenomenon is found to lower the limiting threshold by 30 times and increase the second hyperpolarizability by one and three orders in ps and ns time regimes, respectively.
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Prem Kiran P. et al. Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride // Optics Communications. 2002. Vol. 202. No. 4-6. pp. 347-352.
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Prem Kiran P., NAGA SRINIVAS N. K. M., Raghunath Reddy D., MAIYA B. G., Dharmadhikari A., Sandhu A. S., Gnana Kumar G., Narayana Rao D. Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride // Optics Communications. 2002. Vol. 202. No. 4-6. pp. 347-352.
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RIS
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TY - JOUR
DO - 10.1016/S0030-4018(02)01112-4
UR - https://doi.org/10.1016/S0030-4018(02)01112-4
TI - Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride
T2 - Optics Communications
AU - Prem Kiran, P.
AU - NAGA SRINIVAS, N. K. M.
AU - Raghunath Reddy, D
AU - MAIYA, BHASKAR G.
AU - Dharmadhikari, Aditya
AU - Sandhu, Arvinder S.
AU - Gnana Kumar, G.
AU - Narayana Rao, D.
PY - 2002
DA - 2002/02/01
PB - Elsevier
SP - 347-352
IS - 4-6
VL - 202
SN - 0030-4018
SN - 1873-0310
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2002_Prem Kiran,
author = {P. Prem Kiran and N. K. M. NAGA SRINIVAS and D Raghunath Reddy and BHASKAR G. MAIYA and Aditya Dharmadhikari and Arvinder S. Sandhu and G. Gnana Kumar and D. Narayana Rao},
title = {Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride},
journal = {Optics Communications},
year = {2002},
volume = {202},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/S0030-4018(02)01112-4},
number = {4-6},
pages = {347--352},
doi = {10.1016/S0030-4018(02)01112-4}
}
Cite this
MLA
Copy
Prem Kiran, P., et al. “Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride.” Optics Communications, vol. 202, no. 4-6, Feb. 2002, pp. 347-352. https://doi.org/10.1016/S0030-4018(02)01112-4.