Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques
Publication type: Journal Article
Publication date: 2001-03-01
scimago Q1
wos Q2
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Abstract Effect of phase condition (crystallinity) on the low-temperature radiation-induced degradation of polycarbonate was studied by electron spin resonance (ESR) and infrared (IR) spectroscopy. Semi-crystalline polycarbonate exhibits lower relative yields of radiation-induced degradation in comparison with amorphous polycarbonate, as evidenced by monitoring of both CO and CO2 formation (IR spectroscopy), and radical pair formation (ESR spectroscopy). On the basis of results obtained, the mechanism of electron stabilisation in polycarbonate, and reasons of variation in radical pair inter-spin distance are discussed.
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GOST
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Orlov A. Y. et al. Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques // Polymer. 2001. Vol. 42. No. 5. pp. 1987-1993.
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Orlov A. Y., Feldman V. I. Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques // Polymer. 2001. Vol. 42. No. 5. pp. 1987-1993.
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RIS
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TY - JOUR
DO - 10.1016/S0032-3861(00)00431-6
UR - https://linkinghub.elsevier.com/retrieve/pii/S0032386100004316
TI - Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques
T2 - Polymer
AU - Orlov, A. Yu.
AU - Feldman, Vladimir I.
PY - 2001
DA - 2001/03/01
PB - Elsevier
SP - 1987-1993
IS - 5
VL - 42
SN - 0032-3861
SN - 1873-2291
ER -
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BibTex (up to 50 authors)
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@article{2001_Orlov,
author = {A. Yu. Orlov and Vladimir I. Feldman},
title = {Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques},
journal = {Polymer},
year = {2001},
volume = {42},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0032386100004316},
number = {5},
pages = {1987--1993},
doi = {10.1016/S0032-3861(00)00431-6}
}
Cite this
MLA
Copy
Orlov, A. Yu., et al. “Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques.” Polymer, vol. 42, no. 5, Mar. 2001, pp. 1987-1993. https://linkinghub.elsevier.com/retrieve/pii/S0032386100004316.
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