Polymer

, том 42 , издание 5 , страницы 1987-1993

Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques

A. Yu. Orlov ¹

Vladimir I. Feldman ¹

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Institute of Synthetic Polymeric Materials of RAS, 70 Profsojuznaya Str., Moscow 117393, Russia |

Тип публикации: Journal Article

Дата публикации: 2001-03-01

Elsevier

Polymer

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SJR: 0.843

CiteScore: 7.7

Impact factor: 4.5

ISSN: 00323861, 18732291

DOI: 10.1016/S0032-3861(00)00431-6

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Materials Chemistry

Organic Chemistry

Polymers and Plastics

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Abstract Effect of phase condition (crystallinity) on the low-temperature radiation-induced degradation of polycarbonate was studied by electron spin resonance (ESR) and infrared (IR) spectroscopy. Semi-crystalline polycarbonate exhibits lower relative yields of radiation-induced degradation in comparison with amorphous polycarbonate, as evidenced by monitoring of both CO and CO2 formation (IR spectroscopy), and radical pair formation (ESR spectroscopy). On the basis of results obtained, the mechanism of electron stabilisation in polycarbonate, and reasons of variation in radical pair inter-spin distance are discussed.

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Orlov A. Y. et al. Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques // Polymer. 2001. Vol. 42. No. 5. pp. 1987-1993.

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Orlov A. Y., Feldman V. I. Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques // Polymer. 2001. Vol. 42. No. 5. pp. 1987-1993.

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TY - JOUR

DO - 10.1016/S0032-3861(00)00431-6

UR - https://linkinghub.elsevier.com/retrieve/pii/S0032386100004316

TI - Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques

T2 - Polymer

AU - Orlov, A. Yu.

AU - Feldman, Vladimir I.

PY - 2001

DA - 2001/03/01

PB - Elsevier

SP - 1987-1993

IS - 5

VL - 42

SN - 0032-3861

SN - 1873-2291

ER -

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@article{2001_Orlov,

author = {A. Yu. Orlov and Vladimir I. Feldman},

title = {Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques},

journal = {Polymer},

year = {2001},

volume = {42},

publisher = {Elsevier},

month = {mar},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0032386100004316},

number = {5},

pages = {1987--1993},

doi = {10.1016/S0032-3861(00)00431-6}

}

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Orlov, A. Yu., et al. “Effect of phase condition on the low-temperature radiation-induced degradation of polycarbonate as studied by spectroscopic techniques.” Polymer, vol. 42, no. 5, Mar. 2001, pp. 1987-1993. https://linkinghub.elsevier.com/retrieve/pii/S0032386100004316.