Asymmetric nitrogen—41
Publication type: Journal Article
Publication date: 1985-01-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Abstract The twisting of 5- and 6-membered rings in bicyclic cis-diaziridines—1,5-diazabicyclo [3.1.0]hexanes 12–17 and l,6-diazabicyclo[4.1.0]heptane 18—is a rapid process in the time scale of 1H- and 13C-NMR even at -80°. According to the 1H- and 13C-NMR spectra, 1,5-diazabicyclo [3.1.0]hexanes 12,13,15a,15b and 16a,16b do, exist mostly in the boat form ; only the introduction of endo substituents into position 3 or 6 leads to the population of the chair, as is the case with 14 and 17. 2,4-Dialkyl substituted 1,5-diaza- and 1,3,5-triazabicyclo[3.1.0]hexanes are formed via a transition cyclization state similar in its geometry to the initial chair-shaped N-chlorodi(tri)azanes.
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46
Total citations:
46
Citations from 2025:
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(2.17%)
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MLA
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GOST
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Shustov G. V. et al. Asymmetric nitrogen—41 // Tetrahedron. 1985. Vol. 41. No. 23. pp. 5719-5731.
GOST all authors (up to 50)
Copy
Shustov G. V., Denisenko S. N., Chervin I. I., Asfandiarov N. L., Kostyanovsky R. G. Asymmetric nitrogen—41 // Tetrahedron. 1985. Vol. 41. No. 23. pp. 5719-5731.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0040-4020(01)91378-X
UR - https://doi.org/10.1016/S0040-4020(01)91378-X
TI - Asymmetric nitrogen—41
T2 - Tetrahedron
AU - Shustov, G. V.
AU - Denisenko, S N
AU - Chervin, I. I.
AU - Asfandiarov, Nail' L.
AU - Kostyanovsky, R. G.
PY - 1985
DA - 1985/01/01
PB - Elsevier
SP - 5719-5731
IS - 23
VL - 41
SN - 0040-4020
SN - 1464-5416
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1985_Shustov,
author = {G. V. Shustov and S N Denisenko and I. I. Chervin and Nail' L. Asfandiarov and R. G. Kostyanovsky},
title = {Asymmetric nitrogen—41},
journal = {Tetrahedron},
year = {1985},
volume = {41},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0040-4020(01)91378-X},
number = {23},
pages = {5719--5731},
doi = {10.1016/S0040-4020(01)91378-X}
}
Cite this
MLA
Copy
Shustov, G. V., et al. “Asymmetric nitrogen—41.” Tetrahedron, vol. 41, no. 23, Jan. 1985, pp. 5719-5731. https://doi.org/10.1016/S0040-4020(01)91378-X.
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