Catalyzed dehalogenation of Delor 103 by sodium hydridoaluminate
Publication type: Journal Article
Publication date: 2001-09-01
scimago Q1
SJR: 1.896
CiteScore: 18.1
Impact factor: —
ISSN: 00456535, 18791298
PubMed ID:
11513131
General Chemistry
General Medicine
Environmental Chemistry
Environmental Engineering
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
Pollution
Abstract
The complete dechlorination of PCB liquid Delor 103 (42.6% Cl) to biphenyl has been effected in toluene with sodium dihydridobis(2-methoxyethoxo)aluminate (SDMA) in the presence of catalytic amounts of Ni(II) and Co(II) 2,4-pentanedionates at elevated temperatures. Changes in PCB congeners distribution during dechlorination were monitored by GC(ECD) and GC/MS, and the scheme of their transformation was proposed on the basis of site selectivity observed. A kinetic analysis of the reaction is presented.
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Total citations:
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Citations from 2024:
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GOST
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Hetflejš J. et al. Catalyzed dehalogenation of Delor 103 by sodium hydridoaluminate // Chemosphere. 2001. Vol. 44. No. 6. pp. 1521-1529.
GOST all authors (up to 50)
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Hetflejš J., Czakóová M., Řeřicha R., Včelák J. Catalyzed dehalogenation of Delor 103 by sodium hydridoaluminate // Chemosphere. 2001. Vol. 44. No. 6. pp. 1521-1529.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0045-6535(00)00486-0
UR - https://doi.org/10.1016/S0045-6535(00)00486-0
TI - Catalyzed dehalogenation of Delor 103 by sodium hydridoaluminate
T2 - Chemosphere
AU - Hetflejš, Jiřı́
AU - Czakóová, Marie
AU - Řeřicha, Roman
AU - Včelák, Josef
PY - 2001
DA - 2001/09/01
PB - Elsevier
SP - 1521-1529
IS - 6
VL - 44
PMID - 11513131
SN - 0045-6535
SN - 1879-1298
ER -
Cite this
BibTex (up to 50 authors)
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@article{2001_Hetflejš,
author = {Jiřı́ Hetflejš and Marie Czakóová and Roman Řeřicha and Josef Včelák},
title = {Catalyzed dehalogenation of Delor 103 by sodium hydridoaluminate},
journal = {Chemosphere},
year = {2001},
volume = {44},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0045-6535(00)00486-0},
number = {6},
pages = {1521--1529},
doi = {10.1016/S0045-6535(00)00486-0}
}
Cite this
MLA
Copy
Hetflejš, Jiřı́, et al. “Catalyzed dehalogenation of Delor 103 by sodium hydridoaluminate.” Chemosphere, vol. 44, no. 6, Sep. 2001, pp. 1521-1529. https://doi.org/10.1016/S0045-6535(00)00486-0.