Associative oxygen species on the oxidized silver surface formed under O2 microwave excitation
Publication type: Journal Article
Publication date: 2000-09-01
scimago Q1
wos Q1
SJR: 1.310
CiteScore: 13.4
Impact factor: 6.9
ISSN: 01694332, 18735584
Surfaces, Coatings and Films
General Chemistry
General Physics and Astronomy
Condensed Matter Physics
Surfaces and Interfaces
Abstract
The experimental methods of X-ray and ultraviolet photoelectron spectroscopies (XPS and UPS, respectively) and the quantum mechanical calculations are applied for analysis of oxygen states on the silver oxide surface. At low temperatures ( T <470 K), the silver surface is intensively oxidized by a microwave oxygen discharge to form cuprite Ag 2 O. Two adsorbed oxygen species of the atomic (dissociative) and molecular (associative) nature can be adsorbed on the cuprite Ag 2 O surface. A comparison of the UPS data and the DFT calculations of molecular models Ag 2 –O 2 and Ag 2 –O 3 shows that the formation of ozonide-like structures is preferable to that of peroxide species. Thermal stability and the reaction probability of the adsorbed states are investigated.
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GOST
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Boronin A. et al. Associative oxygen species on the oxidized silver surface formed under O2 microwave excitation // Applied Surface Science. 2000. Vol. 165. No. 1. pp. 9-14.
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Boronin A., Koscheev S., Murzakhmetov K., Avdeev V., Zhidomirov G. Associative oxygen species on the oxidized silver surface formed under O2 microwave excitation // Applied Surface Science. 2000. Vol. 165. No. 1. pp. 9-14.
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RIS
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TY - JOUR
DO - 10.1016/S0169-4332(00)00146-X
UR - https://doi.org/10.1016/S0169-4332(00)00146-X
TI - Associative oxygen species on the oxidized silver surface formed under O2 microwave excitation
T2 - Applied Surface Science
AU - Boronin, Andrei
AU - Koscheev, S.V.
AU - Murzakhmetov, K.T
AU - Avdeev, V.I
AU - Zhidomirov, G.M.
PY - 2000
DA - 2000/09/01
PB - Elsevier
SP - 9-14
IS - 1
VL - 165
SN - 0169-4332
SN - 1873-5584
ER -
Cite this
BibTex (up to 50 authors)
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@article{2000_Boronin,
author = {Andrei Boronin and S.V. Koscheev and K.T Murzakhmetov and V.I Avdeev and G.M. Zhidomirov},
title = {Associative oxygen species on the oxidized silver surface formed under O2 microwave excitation},
journal = {Applied Surface Science},
year = {2000},
volume = {165},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0169-4332(00)00146-X},
number = {1},
pages = {9--14},
doi = {10.1016/S0169-4332(00)00146-X}
}
Cite this
MLA
Copy
Boronin, Andrei, et al. “Associative oxygen species on the oxidized silver surface formed under O2 microwave excitation.” Applied Surface Science, vol. 165, no. 1, Sep. 2000, pp. 9-14. https://doi.org/10.1016/S0169-4332(00)00146-X.
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