Crystal structures and solution dynamics of monocyclopentadienyl titanium(IV) complexes bearing pendant ether and phosphanyl type functionalities
Publication type: Journal Article
Publication date: 2003-09-12
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Two novel half-sandwich Ti(IV) complexes, [η5:η1-O-C5(CH3)4CH2CH2OCH3]TiCl3 (3) and (η5:η1-P-C5H4CH2CH2PPh2)TiCl3 (6), were prepared and structurally characterised. At elevated temperatures, complex 3 undergoes a conversion into [η5:σ-C5(CH3)4CH2CH2O–]TiCl2 (4). The dynamic behaviour of complexes 3 and 6 in solutions has been studied by variable-temperature 1H, 13C and 31P NMR spectroscopy. Thermodynamic parameters of the intramolecular dissociation-coordination processes for 3 and 6 were elucidated by the numerical analysis of the δ(T) dependencies. The intramolecular M(IV)←E (M=Ti, Zr; E=O, P) coordination in half-sandwich cyclopentadienyl complexes is discussed.
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Krut’ko D. P. et al. Crystal structures and solution dynamics of monocyclopentadienyl titanium(IV) complexes bearing pendant ether and phosphanyl type functionalities // Polyhedron. 2003. Vol. 22. No. 21. pp. 2885-2894.
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Krut’ko D. P., Borzov M. V., Veksler E. N., Churakov A. V., Mach K. Crystal structures and solution dynamics of monocyclopentadienyl titanium(IV) complexes bearing pendant ether and phosphanyl type functionalities // Polyhedron. 2003. Vol. 22. No. 21. pp. 2885-2894.
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RIS
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TY - JOUR
DO - 10.1016/S0277-5387(03)00407-8
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538703004078
TI - Crystal structures and solution dynamics of monocyclopentadienyl titanium(IV) complexes bearing pendant ether and phosphanyl type functionalities
T2 - Polyhedron
AU - Krut’ko, Dmitrii P.
AU - Borzov, Maxim V.
AU - Veksler, Eduard N.
AU - Churakov, Andrei V.
AU - Mach, Karel
PY - 2003
DA - 2003/09/12
PB - Elsevier
SP - 2885-2894
IS - 21
VL - 22
SN - 0277-5387
SN - 1873-3719
ER -
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BibTex (up to 50 authors)
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@article{2003_Krut’ko,
author = {Dmitrii P. Krut’ko and Maxim V. Borzov and Eduard N. Veksler and Andrei V. Churakov and Karel Mach},
title = {Crystal structures and solution dynamics of monocyclopentadienyl titanium(IV) complexes bearing pendant ether and phosphanyl type functionalities},
journal = {Polyhedron},
year = {2003},
volume = {22},
publisher = {Elsevier},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538703004078},
number = {21},
pages = {2885--2894},
doi = {10.1016/S0277-5387(03)00407-8}
}
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MLA
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Krut’ko, Dmitrii P., et al. “Crystal structures and solution dynamics of monocyclopentadienyl titanium(IV) complexes bearing pendant ether and phosphanyl type functionalities.” Polyhedron, vol. 22, no. 21, Sep. 2003, pp. 2885-2894. https://linkinghub.elsevier.com/retrieve/pii/S0277538703004078.
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