Elsevier
Polyhedron
,  volume 18 ,  issue 8-9 ,  pages 1159-1162

Synthesis and structure of the phosphinophosphide niobocene complex Cp2Nb(PPh2)(PHPh2)

Publication type: Journal Article
Publication date: 1999-03-01
Elsevier
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The phosphinophosphido niobocene complex Cp 2 Nb(PHPh 2 )(PPh 2 ) ( 2 ) was prepared by deprotonation of the cationic diphosphino complex [Cp 2 Nb(PHPh 2 ) 2 ]Cl ( 3 ). Complex 2 is thermally unstable and readily dissociates phosphine to give the ortho -metallated complex Cp 2 Nb(PHPhC 6 H 4 −). Crystal structure determination of 2 supported its formulation as the phosphinophosphido compound. The Nb–P(1) (phosphino) bond length is 2.524(2) A and Nb–P(2) (phosphido) bond length is 2.610(2) A.
Found 
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Nikonov G. I. et al. Synthesis and structure of the phosphinophosphide niobocene complex Cp2Nb(PPh2)(PHPh2) // Polyhedron. 1999. Vol. 18. No. 8-9. pp. 1159-1162.
GOST all authors (up to 50) Copy
Nikonov G. I., Lemenovskii D. A., Dorogov K. Yu., Churakov A. V. Synthesis and structure of the phosphinophosphide niobocene complex Cp2Nb(PPh2)(PHPh2) // Polyhedron. 1999. Vol. 18. No. 8-9. pp. 1159-1162.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/S0277-5387(98)00408-2
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538798004082
TI - Synthesis and structure of the phosphinophosphide niobocene complex Cp2Nb(PPh2)(PHPh2)
T2 - Polyhedron
AU - Nikonov, G. I.
AU - Lemenovskii, Dmitry A
AU - Dorogov, Konstantin Yu
AU - Churakov, Andrei V.
PY - 1999
DA - 1999/03/01
PB - Elsevier
SP - 1159-1162
IS - 8-9
VL - 18
SN - 0277-5387
SN - 1873-3719
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1999_Nikonov,
author = {G. I. Nikonov and Dmitry A Lemenovskii and Konstantin Yu Dorogov and Andrei V. Churakov},
title = {Synthesis and structure of the phosphinophosphide niobocene complex Cp2Nb(PPh2)(PHPh2)},
journal = {Polyhedron},
year = {1999},
volume = {18},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538798004082},
number = {8-9},
pages = {1159--1162},
doi = {10.1016/S0277-5387(98)00408-2}
}
MLA
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MLA Copy
Nikonov, G. I., et al. “Synthesis and structure of the phosphinophosphide niobocene complex Cp2Nb(PPh2)(PHPh2).” Polyhedron, vol. 18, no. 8-9, Mar. 1999, pp. 1159-1162. https://linkinghub.elsevier.com/retrieve/pii/S0277538798004082.