Elsevier
Polyhedron
,  volume 20 ,  issue 11-14 ,  pages 1355-1357

Ferro- and antiferromagnetic interactions of cyano-substituted thioaminyl radicals

Publication type: Journal Article
Publication date: 2001-05-01
Elsevier
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Four kinds of thioaminyls, N-(arylthio)-2-ethoxycarbonyl- (1), N-(arylthio)-2-acetyl- (2), N-(arylthio)-2-cyano- (3), and N-(arylthio)-2-fluoro-4,6-diarylphenylaminyls (4) were prepared. Thioaminyls 3 were quite persistent and could be isolated as radical crystals. For the isolated three radicals (3a, 3b and 3d) the magnetic susceptibility measurements were carried out using a SQUID magnetometer in the temperature range 1.8–300 K. The magnetic interactions of 3b and 3d were antiferromagnetic, and that of 3a was ferromagnetic. Analysis of the χmolT versus T plots of 3a with the one-dimensional regular Heisenberg model gave 2J/kB=+11.2 K.
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GOST |
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GOST Copy
NAKATSUJI M., MIURA Y., Teki Y. Ferro- and antiferromagnetic interactions of cyano-substituted thioaminyl radicals // Polyhedron. 2001. Vol. 20. No. 11-14. pp. 1355-1357.
GOST all authors (up to 50) Copy
NAKATSUJI M., MIURA Y., Teki Y. Ferro- and antiferromagnetic interactions of cyano-substituted thioaminyl radicals // Polyhedron. 2001. Vol. 20. No. 11-14. pp. 1355-1357.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/s0277-5387(01)00618-0
UR - https://doi.org/10.1016/s0277-5387(01)00618-0
TI - Ferro- and antiferromagnetic interactions of cyano-substituted thioaminyl radicals
T2 - Polyhedron
AU - NAKATSUJI, MASAAKI
AU - MIURA, YOZO
AU - Teki, Y.
PY - 2001
DA - 2001/05/01
PB - Elsevier
SP - 1355-1357
IS - 11-14
VL - 20
SN - 0277-5387
SN - 1873-3719
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2001_NAKATSUJI,
author = {MASAAKI NAKATSUJI and YOZO MIURA and Y. Teki},
title = {Ferro- and antiferromagnetic interactions of cyano-substituted thioaminyl radicals},
journal = {Polyhedron},
year = {2001},
volume = {20},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/s0277-5387(01)00618-0},
number = {11-14},
pages = {1355--1357},
doi = {10.1016/s0277-5387(01)00618-0}
}
MLA
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MLA Copy
NAKATSUJI, MASAAKI, et al. “Ferro- and antiferromagnetic interactions of cyano-substituted thioaminyl radicals.” Polyhedron, vol. 20, no. 11-14, May. 2001, pp. 1355-1357. https://doi.org/10.1016/s0277-5387(01)00618-0.