HeI photoelectron spectra and π-electronic structure of substituted 1,3,2,4-benzodithiadiazines, formally antiaromatic 12π-electron compounds
Тип публикации: Journal Article
Дата публикации: 2000-03-01
scimago Q2
wos Q3
БС2
SJR: 0.601
CiteScore: 3.6
Impact factor: 1.5
ISSN: 03682048, 18732526
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Radiation
Краткое описание
The HeI photoelectron spectra of various 5-R-, 6-R- and 7-R-substituted derivatives of 1,3,2,4-benzodithiadiazine (R=F, Cl, CH3, CF3, OCH3), a formally antiaromatic 12π-electron compound, have been measured and assigned in the IE1–IE4 area by Koopmans’ correlation with 6-31G* eigenvalues. Despite a considerable localization (∼70%) of the highest occupied π-MO on the sulfur–nitrogen fragment, IE1 depends upon both position and character of the carbocyclic substituent R.
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Manaev A. V. et al. HeI photoelectron spectra and π-electronic structure of substituted 1,3,2,4-benzodithiadiazines, formally antiaromatic 12π-electron compounds // Journal of Electron Spectroscopy and Related Phenomena. 2000. Vol. 107. No. 1. pp. 33-38.
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Manaev A. V., A. MAKAROV A., Gatilov Y. V., Latosińska J., Shcherbukhin V. V., Traven V. F., Zibarev A. V. HeI photoelectron spectra and π-electronic structure of substituted 1,3,2,4-benzodithiadiazines, formally antiaromatic 12π-electron compounds // Journal of Electron Spectroscopy and Related Phenomena. 2000. Vol. 107. No. 1. pp. 33-38.
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TY - JOUR
DO - 10.1016/s0368-2048(99)00095-x
UR - https://doi.org/10.1016/s0368-2048(99)00095-x
TI - HeI photoelectron spectra and π-electronic structure of substituted 1,3,2,4-benzodithiadiazines, formally antiaromatic 12π-electron compounds
T2 - Journal of Electron Spectroscopy and Related Phenomena
AU - Manaev, Alexander V.
AU - A. MAKAROV, Alexander
AU - Gatilov, Yuri V.
AU - Latosińska, J.N.
AU - Shcherbukhin, Vladimir V.
AU - Traven, Valery F.
AU - Zibarev, Andrey V.
PY - 2000
DA - 2000/03/01
PB - Elsevier
SP - 33-38
IS - 1
VL - 107
SN - 0368-2048
SN - 1873-2526
ER -
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@article{2000_Manaev,
author = {Alexander V. Manaev and Alexander A. MAKAROV and Yuri V. Gatilov and J.N. Latosińska and Vladimir V. Shcherbukhin and Valery F. Traven and Andrey V. Zibarev},
title = {HeI photoelectron spectra and π-electronic structure of substituted 1,3,2,4-benzodithiadiazines, formally antiaromatic 12π-electron compounds},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
year = {2000},
volume = {107},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/s0368-2048(99)00095-x},
number = {1},
pages = {33--38},
doi = {10.1016/s0368-2048(99)00095-x}
}
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Manaev, Alexander V., et al. “HeI photoelectron spectra and π-electronic structure of substituted 1,3,2,4-benzodithiadiazines, formally antiaromatic 12π-electron compounds.” Journal of Electron Spectroscopy and Related Phenomena, vol. 107, no. 1, Mar. 2000, pp. 33-38. https://doi.org/10.1016/s0368-2048(99)00095-x.