Journal of Alloys and Compounds, volume 346, issue 1-2, pages 129-133
XAS spectra of Ce2[MnN3] at the Ce-M4,5, Ce-L3, Mn-L2,3 and N-K thresholds
Rainer Niewa
1
,
Zhi-Wei Hu
2
,
C. Grazioli
3
,
Ulrich K. Rößler
3
,
Mark Golden
3
,
Martin Knupfer
3
,
J. Fink
3
,
H. Giefers
4
,
G. Wortmann
4
,
F. M. F DE GROOT
5
,
F. J. DiSalvo
6
3
Institut für Festkörper- und Werkstofforschung Dresden, P.O. Box 270116, 01171 Dresden, Germany
|
Publication type: Journal Article
Publication date: 2002-11-01
Journal:
Journal of Alloys and Compounds
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 6.2
ISSN: 09258388
Materials Chemistry
Metals and Alloys
Mechanical Engineering
Mechanics of Materials
Abstract
The X-ray absorption spectroscopy at the Ce-M-4.5, Ce-L-3, Mn-L-2,L-3 and N-K thresholds was used to study the electronic and magnetic structure of the recently obtained Ce-2[MnN3]. Manganese is found to be in a state similar to that in eta-Mn3N2, with strong covalency between Mn and N. The multiple peaked structure in the Ce-M-4.5 and Ce-L-3 XAS spectra indicates that the valence state of cerium in Ce-2[MnN3] is only slightly lower than that found in CeO2 containing Ce-IV with a strong covalent mixture between Ce 4f and ligand 2p states. By simulating the Ce-L-3 XAS spectrum using a simplified Anderson impurity model the 4f occupancy was found to be 0.52 for Ce-2 [MnN3] compared to 0.49 for CeO2 in the ground state. (C) 2002 Elsevier Science B.V. All rights reserved.
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Niewa R. et al. XAS spectra of Ce2[MnN3] at the Ce-M4,5, Ce-L3, Mn-L2,3 and N-K thresholds // Journal of Alloys and Compounds. 2002. Vol. 346. No. 1-2. pp. 129-133.
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Niewa R., Hu Z., Grazioli C., Rößler U. K., Golden M., Knupfer M., Fink J., Giefers H., Wortmann G., DE GROOT F. M. F., DiSalvo F. J. XAS spectra of Ce2[MnN3] at the Ce-M4,5, Ce-L3, Mn-L2,3 and N-K thresholds // Journal of Alloys and Compounds. 2002. Vol. 346. No. 1-2. pp. 129-133.
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TY - JOUR
DO - 10.1016/S0925-8388(02)00519-4
UR - https://doi.org/10.1016/S0925-8388(02)00519-4
TI - XAS spectra of Ce2[MnN3] at the Ce-M4,5, Ce-L3, Mn-L2,3 and N-K thresholds
T2 - Journal of Alloys and Compounds
AU - Niewa, Rainer
AU - Hu, Zhi-Wei
AU - Grazioli, C.
AU - Rößler, Ulrich K.
AU - Golden, Mark
AU - Knupfer, Martin
AU - Fink, J.
AU - Giefers, H.
AU - Wortmann, G.
AU - DE GROOT, F. M. F
AU - DiSalvo, F. J.
PY - 2002
DA - 2002/11/01 00:00:00
PB - Elsevier
SP - 129-133
IS - 1-2
VL - 346
SN - 0925-8388
ER -
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@article{2002_Niewa,
author = {Rainer Niewa and Zhi-Wei Hu and C. Grazioli and Ulrich K. Rößler and Mark Golden and Martin Knupfer and J. Fink and H. Giefers and G. Wortmann and F. M. F DE GROOT and F. J. DiSalvo},
title = {XAS spectra of Ce2[MnN3] at the Ce-M4,5, Ce-L3, Mn-L2,3 and N-K thresholds},
journal = {Journal of Alloys and Compounds},
year = {2002},
volume = {346},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/S0925-8388(02)00519-4},
number = {1-2},
pages = {129--133},
doi = {10.1016/S0925-8388(02)00519-4}
}
Cite this
MLA
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Niewa, Rainer, et al. “XAS spectra of Ce2[MnN3] at the Ce-M4,5, Ce-L3, Mn-L2,3 and N-K thresholds.” Journal of Alloys and Compounds, vol. 346, no. 1-2, Nov. 2002, pp. 129-133. https://doi.org/10.1016/S0925-8388(02)00519-4.
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