Journal of Alloys and Compounds, volume 348, issue 1-2, pages 80-87
Synthesis and characterisation of the ternary nitride, Sr2TaN3
Publication type: Journal Article
Publication date: 2003-01-01
Journal:
Journal of Alloys and Compounds
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 1.103
CiteScore: 11.1
Impact factor: 5.8
ISSN: 09258388
Materials Chemistry
Metals and Alloys
Mechanical Engineering
Mechanics of Materials
Abstract
The ternary nitridotantalate, Sr 2 TaN 3 has been synthesised via the solid state reaction of strontium subnitride, Sr 2 N, with either of the tantalum nitrides TaN or Ta 3 N 5 in a sealed system under argon at elevated temperatures. The structure of Sr 2 TaN 3 was determined for the first time by Rietveld refinement against powder X-ray diffraction data. The compound crystallises with the Ba 2 ZnO 3 structure [monoclinic space group C 2/ c (No.15), a = 5.9835(1) A, b =11.2832(2) A, c =12.5814(2) A, β = 92.26(1)°, V =848.75(2) A 3 , Z =8] and is isostructural with other A II 2 M V N 3 nitrides, Ba 2 TaN 3 , Sr(Ba) 2 NbN 3 and Sr 2 VN 3 . The nitride contains infinite chains of corner-sharing TaN 4 tetrahedral anions, 1 ∞ [TaN 2 N 2/2 ] 4− , with Ta–N distances of 1.83–1.97 A. Magnetic measurements are consistent with a nitridotantalate(V).
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Bowman A., Gregory D. H. Synthesis and characterisation of the ternary nitride, Sr2TaN3 // Journal of Alloys and Compounds. 2003. Vol. 348. No. 1-2. pp. 80-87.
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Bowman A., Gregory D. H. Synthesis and characterisation of the ternary nitride, Sr2TaN3 // Journal of Alloys and Compounds. 2003. Vol. 348. No. 1-2. pp. 80-87.
Cite this
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TY - JOUR
DO - 10.1016/S0925-8388(02)00861-7
UR - https://doi.org/10.1016/S0925-8388(02)00861-7
TI - Synthesis and characterisation of the ternary nitride, Sr2TaN3
T2 - Journal of Alloys and Compounds
AU - Bowman, Amy
AU - Gregory, Duncan H.
PY - 2003
DA - 2003/01/01
PB - Elsevier
SP - 80-87
IS - 1-2
VL - 348
SN - 0925-8388
ER -
Cite this
BibTex
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@article{2003_Bowman,
author = {Amy Bowman and Duncan H. Gregory},
title = {Synthesis and characterisation of the ternary nitride, Sr2TaN3},
journal = {Journal of Alloys and Compounds},
year = {2003},
volume = {348},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0925-8388(02)00861-7},
number = {1-2},
pages = {80--87},
doi = {10.1016/S0925-8388(02)00861-7}
}
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MLA
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Bowman, Amy, and Duncan H. Gregory. “Synthesis and characterisation of the ternary nitride, Sr2TaN3.” Journal of Alloys and Compounds, vol. 348, no. 1-2, Jan. 2003, pp. 80-87. https://doi.org/10.1016/S0925-8388(02)00861-7.