volume 38 issue 1 pages 39-50

Catalytic hydrodechlorination of decachlorobiphenyl

Publication typeJournal Article
Publication date2002-07-26
scimago Q1
wos Q1
SJR5.180
CiteScore38.4
Impact factor21.1
ISSN09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
The hydrodechlorination (HDCl) process of decachlorobiphenyl (the most chlorinated among polychlorinated biphenyls (PCBs)) promoted by a presulphided NiMo/γ-Al2O3 catalyst has been studied. The experimental runs were carried out in a stirred batch reactor at constant temperature and pressure using hexadecane as reaction medium. Temperature levels T=250 and 300 °C at hydrogen pressure PH2=20 bar were tested. The kinetic analysis of both the overall hydrodechlorination process (organic chlorine→inorganic chlorine) and of the partial network (decachlorobiphenyl→nonachlorobiphenyls→products) was performed and the corresponding kinetic constants have been evaluated. The HDCl process was completed in about 240 min at T=250 °C and in
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GOST |
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GOST Copy
Murena F., Gioia F. Catalytic hydrodechlorination of decachlorobiphenyl // Applied Catalysis B: Environmental. 2002. Vol. 38. No. 1. pp. 39-50.
GOST all authors (up to 50) Copy
Murena F., Gioia F. Catalytic hydrodechlorination of decachlorobiphenyl // Applied Catalysis B: Environmental. 2002. Vol. 38. No. 1. pp. 39-50.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/s0926-3373(02)00025-5
UR - https://doi.org/10.1016/s0926-3373(02)00025-5
TI - Catalytic hydrodechlorination of decachlorobiphenyl
T2 - Applied Catalysis B: Environmental
AU - Murena, Fabio
AU - Gioia, F
PY - 2002
DA - 2002/07/26
PB - Elsevier
SP - 39-50
IS - 1
VL - 38
SN - 0926-3373
SN - 1873-3883
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2002_Murena,
author = {Fabio Murena and F Gioia},
title = {Catalytic hydrodechlorination of decachlorobiphenyl},
journal = {Applied Catalysis B: Environmental},
year = {2002},
volume = {38},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/s0926-3373(02)00025-5},
number = {1},
pages = {39--50},
doi = {10.1016/s0926-3373(02)00025-5}
}
MLA
Cite this
MLA Copy
Murena, Fabio, and F Gioia. “Catalytic hydrodechlorination of decachlorobiphenyl.” Applied Catalysis B: Environmental, vol. 38, no. 1, Jul. 2002, pp. 39-50. https://doi.org/10.1016/s0926-3373(02)00025-5.