H/D exchange between light alkanes and deuterated strong acids. Competition between regiospecific isotope exchange and skeletal rearrangement: an 1H/2H NMR study
Тип публикации: Journal Article
Дата публикации: 1999-05-17
SCImago Q2
WOS Q2
БС1
SJR: 0.892
CiteScore: 8.3
Impact factor: 4.8
ISSN: 0926860X, 18733875
Catalysis
Process Chemistry and Technology
Краткое описание
The deuterium distribution observed in 3-ethylpentane when it is in contact with D2O-exchanged USY zeolite at temperatures as low as 70°C shows that for some alkanes the skeletal rearrangement of the intermediate tertiary carbenium ion can be much faster than the de- and reprotonation reaction which is at the origin of the observed, generally regiospecific, isotope exchange. This behavior is notably increased when the solid acid is replaced by D2SO4 in which the hydride transfer is less efficient.
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Applied Catalysis A: General
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Progress in Nuclear Magnetic Resonance Spectroscopy
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Sommer J. H/D exchange between light alkanes and deuterated strong acids. Competition between regiospecific isotope exchange and skeletal rearrangement: an 1H/2H NMR study // Applied Catalysis A: General. 1999. Vol. 181. No. 2. pp. 257-265.
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Sommer J. H/D exchange between light alkanes and deuterated strong acids. Competition between regiospecific isotope exchange and skeletal rearrangement: an 1H/2H NMR study // Applied Catalysis A: General. 1999. Vol. 181. No. 2. pp. 257-265.
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TY - JOUR
DO - 10.1016/s0926-860x(98)00409-8
UR - https://doi.org/10.1016/s0926-860x(98)00409-8
TI - H/D exchange between light alkanes and deuterated strong acids. Competition between regiospecific isotope exchange and skeletal rearrangement: an 1H/2H NMR study
T2 - Applied Catalysis A: General
AU - Sommer, J
PY - 1999
DA - 1999/05/17
PB - Elsevier
SP - 257-265
IS - 2
VL - 181
SN - 0926-860X
SN - 1873-3875
ER -
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BibTex (до 50 авторов)
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@article{1999_Sommer,
author = {J Sommer},
title = {H/D exchange between light alkanes and deuterated strong acids. Competition between regiospecific isotope exchange and skeletal rearrangement: an 1H/2H NMR study},
journal = {Applied Catalysis A: General},
year = {1999},
volume = {181},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/s0926-860x(98)00409-8},
number = {2},
pages = {257--265},
doi = {10.1016/s0926-860x(98)00409-8}
}
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MLA
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Sommer, J.. “H/D exchange between light alkanes and deuterated strong acids. Competition between regiospecific isotope exchange and skeletal rearrangement: an 1H/2H NMR study.” Applied Catalysis A: General, vol. 181, no. 2, May. 1999, pp. 257-265. https://doi.org/10.1016/s0926-860x(98)00409-8.
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