Easy preparation of enantiopure C2-symmetrical aminoalcohols derived from m-xylylene diamine.
Publication type: Journal Article
Publication date: 1994-01-01
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The title compounds were prepared by condensation of isophthaldehyde with chiral amino alcohols or α-amino esters in three different ways depending on the substitution pattern. These methods are: for N-substituted amino alcohols, by reduction of the epimeric mixtures of 1,3-oxazolidines formed in the condensation process; for unsubstituted ones, by reduction of the corresponding hydroxy imines, followed by N-alkylation; and for the imines obtained in the condensation with amino esters, by sequential reduction and reaction with methylmagnesium iodide.
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Andrés J. M. et al. Easy preparation of enantiopure C2-symmetrical aminoalcohols derived from m-xylylene diamine. // Tetrahedron Asymmetry. 1994. Vol. 5. No. 1. pp. 57-66.
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Andrés J. M., Martínez M. A., Pedrosa R., Pérez-Encabo A. Easy preparation of enantiopure C2-symmetrical aminoalcohols derived from m-xylylene diamine. // Tetrahedron Asymmetry. 1994. Vol. 5. No. 1. pp. 57-66.
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TY - JOUR
DO - 10.1016/s0957-4166(00)80484-x
UR - https://doi.org/10.1016/s0957-4166(00)80484-x
TI - Easy preparation of enantiopure C2-symmetrical aminoalcohols derived from m-xylylene diamine.
T2 - Tetrahedron Asymmetry
AU - Andrés, José M
AU - Martínez, Maria A
AU - Pedrosa, Rafael
AU - Pérez-Encabo, Alfonso
PY - 1994
DA - 1994/01/01
PB - Elsevier
SP - 57-66
IS - 1
VL - 5
SN - 0957-4166
SN - 1362-511X
ER -
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@article{1994_Andrés,
author = {José M Andrés and Maria A Martínez and Rafael Pedrosa and Alfonso Pérez-Encabo},
title = {Easy preparation of enantiopure C2-symmetrical aminoalcohols derived from m-xylylene diamine.},
journal = {Tetrahedron Asymmetry},
year = {1994},
volume = {5},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/s0957-4166(00)80484-x},
number = {1},
pages = {57--66},
doi = {10.1016/s0957-4166(00)80484-x}
}
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MLA
Copy
Andrés, José M., et al. “Easy preparation of enantiopure C2-symmetrical aminoalcohols derived from m-xylylene diamine..” Tetrahedron Asymmetry, vol. 5, no. 1, Jan. 1994, pp. 57-66. https://doi.org/10.1016/s0957-4166(00)80484-x.