Novel chiral water soluble phosphines I. Preparation and characterization of amine functionalized DIOP, Chiraphos, and BDPP derivatives and quaternization of their rhodium complexes
Тип публикации: Journal Article
Дата публикации: 1990-01-01
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Synthetic details for the preparation of tetra-amine functionalized derivatives of the ligands BDPP, Chiraphos, and DIOP (2,4-bis(-bis(-p-N,N-dimethylaminophenyl)phosphino)pentane; 2,3-bis(-bis(-p-N,N-dimethylaminophenyl)-phosphino)butane; and 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(-bis(-p-N,N-dimethylaminophenyl)phosphino)butane; respectively). The ligands are conveniently quaternized in their rhodium diene complexes with (CH 3 ) 3 OBF 4 . Both the methyl quaternized and proton quaternized versions of the rhodium complexes have unlimited water solubility.
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Tóth I. H., Hanson B. E. Novel chiral water soluble phosphines I. Preparation and characterization of amine functionalized DIOP, Chiraphos, and BDPP derivatives and quaternization of their rhodium complexes // Tetrahedron Asymmetry. 1990. Vol. 1. No. 12. pp. 895-912.
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Tóth I. H., Hanson B. E. Novel chiral water soluble phosphines I. Preparation and characterization of amine functionalized DIOP, Chiraphos, and BDPP derivatives and quaternization of their rhodium complexes // Tetrahedron Asymmetry. 1990. Vol. 1. No. 12. pp. 895-912.
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TY - JOUR
DO - 10.1016/S0957-4166(00)82281-8
UR - https://doi.org/10.1016/S0957-4166(00)82281-8
TI - Novel chiral water soluble phosphines I. Preparation and characterization of amine functionalized DIOP, Chiraphos, and BDPP derivatives and quaternization of their rhodium complexes
T2 - Tetrahedron Asymmetry
AU - Tóth, Imre H.
AU - Hanson, Brian E.
PY - 1990
DA - 1990/01/01
PB - Elsevier
SP - 895-912
IS - 12
VL - 1
SN - 0957-4166
SN - 1362-511X
ER -
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@article{1990_Tóth,
author = {Imre H. Tóth and Brian E. Hanson},
title = {Novel chiral water soluble phosphines I. Preparation and characterization of amine functionalized DIOP, Chiraphos, and BDPP derivatives and quaternization of their rhodium complexes},
journal = {Tetrahedron Asymmetry},
year = {1990},
volume = {1},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0957-4166(00)82281-8},
number = {12},
pages = {895--912},
doi = {10.1016/S0957-4166(00)82281-8}
}
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MLA
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Tóth, Imre, et al. “Novel chiral water soluble phosphines I. Preparation and characterization of amine functionalized DIOP, Chiraphos, and BDPP derivatives and quaternization of their rhodium complexes.” Tetrahedron Asymmetry, vol. 1, no. 12, Jan. 1990, pp. 895-912. https://doi.org/10.1016/S0957-4166(00)82281-8.
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