New chiral phosphole ligands: their coordination behaviour and application in palladium-catalysed asymmetric allylic substitution
Тип публикации: Journal Article
Дата публикации: 2002-06-01
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
New chiral 1-pyrrolidinophosphole ligands have been synthesised. These phospholes behave as monodentate ligands towards transition metal centres giving mononuclear disubstituted phosphole complexes of the type [M(phosphole) 2 Cl 2 ] with palladium(II) and platinum(II) precursors. In the palladium-catalysed asymmetric allylic substitution of 1,3-diphenyl-2-enylacetate with the anion of dimethylmalonate, the palladium and platinum complexes of these ligands proved to be efficient catalysts for the alkylation reaction, but provided only moderate enantioselectivities.
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ГОСТ
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Hydrio J. et al. New chiral phosphole ligands: their coordination behaviour and application in palladium-catalysed asymmetric allylic substitution // Tetrahedron Asymmetry. 2002. Vol. 13. No. 10. pp. 1097-1102.
ГОСТ со всеми авторами (до 50)
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Hydrio J., Gouygou M., Dallemer F., Daran J., Balavoine G. G. New chiral phosphole ligands: their coordination behaviour and application in palladium-catalysed asymmetric allylic substitution // Tetrahedron Asymmetry. 2002. Vol. 13. No. 10. pp. 1097-1102.
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TY - JOUR
DO - 10.1016/s0957-4166(02)00256-2
UR - https://doi.org/10.1016/s0957-4166(02)00256-2
TI - New chiral phosphole ligands: their coordination behaviour and application in palladium-catalysed asymmetric allylic substitution
T2 - Tetrahedron Asymmetry
AU - Hydrio, Jérôme
AU - Gouygou, Maryse
AU - Dallemer, Frédéric
AU - Daran, Jean-Claude
AU - Balavoine, Gilbert G.A.
PY - 2002
DA - 2002/06/01
PB - Elsevier
SP - 1097-1102
IS - 10
VL - 13
SN - 0957-4166
SN - 1362-511X
ER -
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BibTex (до 50 авторов)
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@article{2002_Hydrio,
author = {Jérôme Hydrio and Maryse Gouygou and Frédéric Dallemer and Jean-Claude Daran and Gilbert G.A. Balavoine},
title = {New chiral phosphole ligands: their coordination behaviour and application in palladium-catalysed asymmetric allylic substitution},
journal = {Tetrahedron Asymmetry},
year = {2002},
volume = {13},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/s0957-4166(02)00256-2},
number = {10},
pages = {1097--1102},
doi = {10.1016/s0957-4166(02)00256-2}
}
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MLA
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Hydrio, Jérôme, et al. “New chiral phosphole ligands: their coordination behaviour and application in palladium-catalysed asymmetric allylic substitution.” Tetrahedron Asymmetry, vol. 13, no. 10, Jun. 2002, pp. 1097-1102. https://doi.org/10.1016/s0957-4166(02)00256-2.
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