Selective localization of primary radiation-chemical events in solid aliphatic hydrocarbons and related polymers as evidenced by ESR
Publication type: Journal Article
Publication date: 1996-11-01
scimago Q2
wos Q2
SJR: 0.408
CiteScore: 3.2
Impact factor: 1.8
ISSN: 09698043, 18729800
Radiation
Abstract
Abstract The selectivity of formation of primary radicals in irradiated solid hydrocarbons and related polymers is analyzed on the basis of ESR studies at low and super-low temperatures. The first direct experimental evidence for selective localization of the primary alkyl radicals at conformational defects (gauche conformers) was obtained for high-density oriented polyethylene irradiated at 15K. This result implies highly selective primary CH bond rupture, which correlates with the structure of the ionized molecules of linear alkanes. The correlation between the spin density distribution in the primary hydrocarbon radical cations and the initial mode of radical formation in the corresponding polymers is discussed.
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11
Citations from 2024:
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GOST
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Feldman V. I. Selective localization of primary radiation-chemical events in solid aliphatic hydrocarbons and related polymers as evidenced by ESR // Applied Radiation and Isotopes. 1996. Vol. 47. No. 11-12. pp. 1497-1501.
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Feldman V. I. Selective localization of primary radiation-chemical events in solid aliphatic hydrocarbons and related polymers as evidenced by ESR // Applied Radiation and Isotopes. 1996. Vol. 47. No. 11-12. pp. 1497-1501.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0969-8043(96)00243-6
UR - https://linkinghub.elsevier.com/retrieve/pii/S0969804396002436
TI - Selective localization of primary radiation-chemical events in solid aliphatic hydrocarbons and related polymers as evidenced by ESR
T2 - Applied Radiation and Isotopes
AU - Feldman, V I
PY - 1996
DA - 1996/11/01
PB - Elsevier
SP - 1497-1501
IS - 11-12
VL - 47
SN - 0969-8043
SN - 1872-9800
ER -
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BibTex (up to 50 authors)
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@article{1996_Feldman,
author = {V I Feldman},
title = {Selective localization of primary radiation-chemical events in solid aliphatic hydrocarbons and related polymers as evidenced by ESR},
journal = {Applied Radiation and Isotopes},
year = {1996},
volume = {47},
publisher = {Elsevier},
month = {nov},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0969804396002436},
number = {11-12},
pages = {1497--1501},
doi = {10.1016/S0969-8043(96)00243-6}
}
Cite this
MLA
Copy
Feldman, V. I.. “Selective localization of primary radiation-chemical events in solid aliphatic hydrocarbons and related polymers as evidenced by ESR.” Applied Radiation and Isotopes, vol. 47, no. 11-12, Nov. 1996, pp. 1497-1501. https://linkinghub.elsevier.com/retrieve/pii/S0969804396002436.
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