, volume 55 , issue 5-6 , pages 565-571

Radiation-induced transformations of isolated organic molecules in solid rare gas matrices

Vladimir I. Feldman ¹

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Karpov Institute of Physical Chemistry and Institute of Synthetic Polymeric Materials of RAS, Vorontsovo Pole Str. 10, Moscow 103064, Russia

Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

Karpov Institute of Physical Chemistry

Publication type: Journal Article

Publication date: 1999-08-01

Elsevier

Radiation Physics and Chemistry

scimago Q2

wos Q1

SJR: 0.543

CiteScore: 5.6

Impact factor: 3.3

ISSN: 0969806X, 18790895

DOI: 10.1016/S0969-806X(99)00247-9

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Radiation

Abstract

The radiation-chemical behaviour of isolated organic molecules in solid rare gas matrices was studied using a combination of ESR and IR spectroscopy. The total radiation-chemical yields of degradation of organic molecules in solid argon and xenon were estimated. The effect of electron scavengers on the radiolysis of organic molecules in solid rare gases reveals that the main primary process is positive hole transfer from matrix to guest molecule. ESR spectra of a number of radical cations (alkanes, ethers, arenes) were characterized in a low-disturbing environment. It was found that the electronic characteristics (IP, polarizability) of the matrix used had crucial effect on trapping and reactions of the isolated radical cations.

Found

13 citations

Tyurin Daniil

🥼 🤝

PhD in Chemistry

69 publications, 680 citations

h-index: 15

Lomonosov Moscow State University

Computational chemistry

Computational methods in chemistry

Cryogenic technology

EPR spectroscopy

High-performance computing

IR spectroscopy

Interaction of X-ray and synchrotron radiation with matter

Matrix isolation

Molecular modeling

Molecular spectroscopy

Non-covalent Interactions

Non-valent interactions

1 citation

Davydova Maria

PhD in Chemistry

42 publications, 797 citations

h-index: 16

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Research interests

Circularly polarized luminescence

Clusters

Coordination chemistry

Coordination polymers

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Feldman V. I. Radiation-induced transformations of isolated organic molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1999. Vol. 55. No. 5-6. pp. 565-571.

GOST all authors (up to 50) Copy

Feldman V. I. Radiation-induced transformations of isolated organic molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1999. Vol. 55. No. 5-6. pp. 565-571.

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TY - JOUR

DO - 10.1016/S0969-806X(99)00247-9

UR - https://linkinghub.elsevier.com/retrieve/pii/S0969806X99002479

TI - Radiation-induced transformations of isolated organic molecules in solid rare gas matrices

T2 - Radiation Physics and Chemistry

AU - Feldman, Vladimir I.

PY - 1999

DA - 1999/08/01

PB - Elsevier

SP - 565-571

IS - 5-6

VL - 55

SN - 0969-806X

SN - 1879-0895

ER -

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@article{1999_Feldman,

author = {Vladimir I. Feldman},

title = {Radiation-induced transformations of isolated organic molecules in solid rare gas matrices},

journal = {Radiation Physics and Chemistry},

year = {1999},

volume = {55},

publisher = {Elsevier},

month = {aug},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0969806X99002479},

number = {5-6},

pages = {565--571},

doi = {10.1016/S0969-806X(99)00247-9}

}

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Feldman, Vladimir I.. “Radiation-induced transformations of isolated organic molecules in solid rare gas matrices.” Radiation Physics and Chemistry, vol. 55, no. 5-6, Aug. 1999, pp. 565-571. https://linkinghub.elsevier.com/retrieve/pii/S0969806X99002479.