130GHz ESEEM induced by electron–electron interaction in biradical
Publication type: Journal Article
Publication date: 2002-12-27
scimago Q2
wos Q2
SJR: 0.554
CiteScore: 4.2
Impact factor: 1.9
ISSN: 10907807, 10960856
Biochemistry
Biophysics
Condensed Matter Physics
Nuclear and High Energy Physics
Abstract
A three-pulse stimulated ESE at 130 GHz (D-band) of nitroxide biradical in a molecular glass shows envelope modulation (ESEEM) when the time separation between the first and the second pulses is varied. This ESEEM originates from relaxation-induced flips of the spin partner during the mixing period between the second and third pulses. These flips alternates the local dipolar field in which the resonant spins precess before second and after third pulses. The ESEEM is different for different spectral positions, due to orientation selectivity. For toluene glassy solution at 35 K Fourier transform shows pronounced peak reflecting singularity of the Pake resonance pattern. Increasing temperature up to 80 K results in appearance of a strong additional peak ascribed to alteration of the resonance field induced by methyl group reorientation.
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Total citations:
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Citations from 2025:
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GOST
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Kulik L. V., Paschenko S., Dzuba S. A. 130GHz ESEEM induced by electron–electron interaction in biradical // Journal of Magnetic Resonance. 2002. Vol. 159. No. 2. pp. 237-241.
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Kulik L. V., Paschenko S., Dzuba S. A. 130GHz ESEEM induced by electron–electron interaction in biradical // Journal of Magnetic Resonance. 2002. Vol. 159. No. 2. pp. 237-241.
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RIS
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TY - JOUR
DO - 10.1016/s1090-7807(02)00038-1
UR - https://doi.org/10.1016/s1090-7807(02)00038-1
TI - 130GHz ESEEM induced by electron–electron interaction in biradical
T2 - Journal of Magnetic Resonance
AU - Kulik, Leonid V.
AU - Paschenko, S.V
AU - Dzuba, Sergei A.
PY - 2002
DA - 2002/12/27
PB - Elsevier
SP - 237-241
IS - 2
VL - 159
SN - 1090-7807
SN - 1096-0856
ER -
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BibTex (up to 50 authors)
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@article{2002_Kulik,
author = {Leonid V. Kulik and S.V Paschenko and Sergei A. Dzuba},
title = {130GHz ESEEM induced by electron–electron interaction in biradical},
journal = {Journal of Magnetic Resonance},
year = {2002},
volume = {159},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/s1090-7807(02)00038-1},
number = {2},
pages = {237--241},
doi = {10.1016/s1090-7807(02)00038-1}
}
Cite this
MLA
Copy
Kulik, Leonid V., et al. “130GHz ESEEM induced by electron–electron interaction in biradical.” Journal of Magnetic Resonance, vol. 159, no. 2, Dec. 2002, pp. 237-241. https://doi.org/10.1016/s1090-7807(02)00038-1.