Open Access
Solid State Sciences, volume 5, issue 7, pages 1033-1036
Synthesis, structure and magnetic properties of the ternary nitride La3V2N6
Publication type: Journal Article
Publication date: 2003-07-01
Journal:
Solid State Sciences
Quartile SCImago
Q2
Quartile WOS
Q2
SJR: 0.581
CiteScore: 6.6
Impact factor: 3.4
ISSN: 12932558
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Using gallium as a flux we were able to synthesize the rare earth – transition metal ternary nitride La 3 V 2 N 6 . This compound crystallizes in the tetragonal space group I 4/ mmm (No. 139) with a = b =3.9050(3) Å and c =20.215(2) Å. It is isostructural with the recently discovered ternary nitrides Ln 3 T 2 N 6 (Ln=La, Ce or Pr; T=Nb or Ta) and with the high T c superconducting copper oxide La 2− x Sr x CaCu 2 O 6 . LAPW band structure calculations show that Ln 3 V 2 N 6 contains VN 2 conducting layers. However, magnetic measurements show that La 3 V 2 N 6 is not a high T c superconductor. A comparison between Ln 3 V 2 N 6 and the cuprates is attempted to understand the discrepancy in their electronic behavior. Graphic
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Gál Z., Cario L., DiSalvo F. J. Synthesis, structure and magnetic properties of the ternary nitride La3V2N6 // Solid State Sciences. 2003. Vol. 5. No. 7. pp. 1033-1036.
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Gál Z., Cario L., DiSalvo F. J. Synthesis, structure and magnetic properties of the ternary nitride La3V2N6 // Solid State Sciences. 2003. Vol. 5. No. 7. pp. 1033-1036.
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TY - JOUR
DO - 10.1016/s1293-2558(03)00135-3
UR - https://doi.org/10.1016/s1293-2558(03)00135-3
TI - Synthesis, structure and magnetic properties of the ternary nitride La3V2N6
T2 - Solid State Sciences
AU - Gál, Zoltán
AU - Cario, Laurent
AU - DiSalvo, Francis J.
PY - 2003
DA - 2003/07/01
PB - Elsevier
SP - 1033-1036
IS - 7
VL - 5
SN - 1293-2558
ER -
Cite this
BibTex
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@article{2003_Gál,
author = {Zoltán Gál and Laurent Cario and Francis J. DiSalvo},
title = {Synthesis, structure and magnetic properties of the ternary nitride La3V2N6},
journal = {Solid State Sciences},
year = {2003},
volume = {5},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/s1293-2558(03)00135-3},
number = {7},
pages = {1033--1036},
doi = {10.1016/s1293-2558(03)00135-3}
}
Cite this
MLA
Copy
Gál, Zoltán, et al. “Synthesis, structure and magnetic properties of the ternary nitride La3V2N6.” Solid State Sciences, vol. 5, no. 7, Jul. 2003, pp. 1033-1036. https://doi.org/10.1016/s1293-2558(03)00135-3.