Dimer formation in alkali metal complexes of 15- and 18-Membered indole-containing lariat ether amides
Publication type: Journal Article
Publication date: 2001-05-01
Materials Chemistry
General Chemistry
Organic Chemistry
Inorganic Chemistry
Abstract
Two sodium macrocyclic azaether complexes are reported. In both cases, the sidearms are attached to macroring nitrogen and derive from 4-(3-indolyl)butyric acid. These are the first alkali metal complexes of 15- or 18-membered ring crown amides. In both cases, dimer structures are observed by X-ray crystallographic analysis. Seven oxygen donors are involved in complexing Na+ in the 15-membered ring case, and a symmetrical dimer forms with the 18-membered compound. In the latter case, each Na+ ion is coordinated by 5 ether oxygens from each macrocycle and a carbonyl group from an adjacent macrocycle making Na+ 6-coordinate. In neither case does the counterion interact with the ring-bound cation.
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Meadows E. S. et al. Dimer formation in alkali metal complexes of 15- and 18-Membered indole-containing lariat ether amides // Journal of Supramolecular Chemistry. 2001. Vol. 1. No. 3. pp. 111-115.
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Meadows E. S., Barbour L. J., Ferdani R., Gokel G. W. Dimer formation in alkali metal complexes of 15- and 18-Membered indole-containing lariat ether amides // Journal of Supramolecular Chemistry. 2001. Vol. 1. No. 3. pp. 111-115.
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TY - JOUR
DO - 10.1016/S1472-7862(01)00016-8
UR - https://doi.org/10.1016/S1472-7862(01)00016-8
TI - Dimer formation in alkali metal complexes of 15- and 18-Membered indole-containing lariat ether amides
T2 - Journal of Supramolecular Chemistry
AU - Meadows, Eric S.
AU - Barbour, Leonard J.
AU - Ferdani, Riccardo
AU - Gokel, George W.
PY - 2001
DA - 2001/05/01
PB - Elsevier
SP - 111-115
IS - 3
VL - 1
SN - 1472-7862
ER -
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@article{2001_Meadows,
author = {Eric S. Meadows and Leonard J. Barbour and Riccardo Ferdani and George W. Gokel},
title = {Dimer formation in alkali metal complexes of 15- and 18-Membered indole-containing lariat ether amides},
journal = {Journal of Supramolecular Chemistry},
year = {2001},
volume = {1},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/S1472-7862(01)00016-8},
number = {3},
pages = {111--115},
doi = {10.1016/S1472-7862(01)00016-8}
}
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MLA
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Meadows, Eric S., et al. “Dimer formation in alkali metal complexes of 15- and 18-Membered indole-containing lariat ether amides.” Journal of Supramolecular Chemistry, vol. 1, no. 3, May. 2001, pp. 111-115. https://doi.org/10.1016/S1472-7862(01)00016-8.