New organophosphorus calix[4]arene ionophores for trivalent lanthanide and actinide cations
L Atamas
1
,
O Klimchuk
1
,
V Rudzevich
1
,
V Pirozhenko
1
,
Vitaly Kalchenko
1
,
I. Smirnov
2
,
Vasily A. Babain
2
,
T Efremova
2
,
A. A. Varnek
3
,
Georges Wipff
3
,
F Arnaud-Neu
4
,
M. Roch
4
,
M. Saadioui
5
,
V. Böhmer
5
1
Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, 02094 Kiev 94, Ukraine
|
3
4
Laboratoire de Chimie Physique, UMR 7512 (ULP CNRS), ECPM, 25, rue Becquerel, 67087 Strasbourg, Cedex 02, France
|
5
J. Gutenberg-Universität, Fachbereich Chemie u. Pharmazie, Abteilung Lehramt Chemie, Duesbergweg 10-14, D-55099 Mainz, Germany
|
Publication type: Journal Article
Publication date: 2002-08-01
Materials Chemistry
General Chemistry
Organic Chemistry
Inorganic Chemistry
Abstract
New calix[4]arene phosphoryl derivatives have been synthesized, starting from a calix[4]arene (cone conformer) bearing four P(O)–H functional groups at the wide rim as synthon. Their binding properties towards trivalent lanthanide and actinide cations are investigated by complexation studies in methanol, and liquid–liquid extraction studies. The carbamoylmethylphosphine oxide and diphosphine dioxide derivatives display the ‘calixarene effect’, i.e., they are more efficient than their constitutive binding sites. The studies also reveal the importance of the attachment mode of CMPO-functions to the calixarene platform for the cation binding properties.
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GOST
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Atamas L. et al. New organophosphorus calix[4]arene ionophores for trivalent lanthanide and actinide cations // Journal of Supramolecular Chemistry. 2002. Vol. 2. No. 4-5. pp. 421-427.
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Atamas L., Klimchuk O., Rudzevich V., Pirozhenko V., Kalchenko V., Smirnov I., Babain V. A., Efremova T., Varnek A. A., Wipff G., Arnaud-Neu F., Roch M., Saadioui M., Böhmer V. New organophosphorus calix[4]arene ionophores for trivalent lanthanide and actinide cations // Journal of Supramolecular Chemistry. 2002. Vol. 2. No. 4-5. pp. 421-427.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S1472-7862(03)00052-2
UR - https://doi.org/10.1016/S1472-7862(03)00052-2
TI - New organophosphorus calix[4]arene ionophores for trivalent lanthanide and actinide cations
T2 - Journal of Supramolecular Chemistry
AU - Atamas, L
AU - Klimchuk, O
AU - Rudzevich, V
AU - Pirozhenko, V
AU - Kalchenko, Vitaly
AU - Smirnov, I.
AU - Babain, Vasily A.
AU - Efremova, T
AU - Varnek, A. A.
AU - Wipff, Georges
AU - Arnaud-Neu, F
AU - Roch, M.
AU - Saadioui, M.
AU - Böhmer, V.
PY - 2002
DA - 2002/08/01
PB - Elsevier
SP - 421-427
IS - 4-5
VL - 2
SN - 1472-7862
ER -
Cite this
BibTex (up to 50 authors)
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@article{2002_Atamas,
author = {L Atamas and O Klimchuk and V Rudzevich and V Pirozhenko and Vitaly Kalchenko and I. Smirnov and Vasily A. Babain and T Efremova and A. A. Varnek and Georges Wipff and F Arnaud-Neu and M. Roch and M. Saadioui and V. Böhmer},
title = {New organophosphorus calix[4]arene ionophores for trivalent lanthanide and actinide cations},
journal = {Journal of Supramolecular Chemistry},
year = {2002},
volume = {2},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/S1472-7862(03)00052-2},
number = {4-5},
pages = {421--427},
doi = {10.1016/S1472-7862(03)00052-2}
}
Cite this
MLA
Copy
Atamas, L., et al. “New organophosphorus calix[4]arene ionophores for trivalent lanthanide and actinide cations.” Journal of Supramolecular Chemistry, vol. 2, no. 4-5, Aug. 2002, pp. 421-427. https://doi.org/10.1016/S1472-7862(03)00052-2.
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