Applied Catalysis A: General

, volume 271 , issue 1-2 , pages 69-76

Hydrodechlorination of 1,1,1-trichloroethane over silica-supported palladium catalyst

TOHRU MORI ¹

Jun Kubo ¹

Yutaka Morikawa ¹

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Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta‐cho, Midori‐ku, Yokohama 226‐8503, Japan |

Publication type: Journal Article

Publication date: 2004-09-01

Elsevier

Applied Catalysis A: General

scimago Q2

wos Q2

SJR: 1.000

CiteScore: 8.6

Impact factor: 4.8

ISSN: 0926860X, 18733875

DOI: 10.1016/j.apcata.2004.02.047

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Catalysis

Process Chemistry and Technology

Abstract

Hydrodechlorination of 1,1,1-trichloroethane (CH 3 CCl 3 ) over silica-supported palladium catalyst was studied in a conventional flow reactor at atmospheric pressure. The main product was CH 3 CH 3 and its selectivity was in the range of 75–90% regardless of the reaction temperatures and the composition of reaction mixture. The rest was mainly occupied by partially hydrodechlorinated products, CH 3 CHCl 2 and CH 3 CH 2 Cl, and a coupling product, n -C 4 H 10 . The contact time dependence of product distribution showed that the all products were formed by parallel reactions. A reaction mechanism is proposed, which involves rapid dechlorination of CH 3 CCl 3 into ethylidyne species.

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MORI T., Kubo J., Morikawa Y. Hydrodechlorination of 1,1,1-trichloroethane over silica-supported palladium catalyst // Applied Catalysis A: General. 2004. Vol. 271. No. 1-2. pp. 69-76.

GOST all authors (up to 50) Copy

MORI T., Kubo J., Morikawa Y. Hydrodechlorination of 1,1,1-trichloroethane over silica-supported palladium catalyst // Applied Catalysis A: General. 2004. Vol. 271. No. 1-2. pp. 69-76.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.apcata.2004.02.047

UR - https://doi.org/10.1016/j.apcata.2004.02.047

TI - Hydrodechlorination of 1,1,1-trichloroethane over silica-supported palladium catalyst

T2 - Applied Catalysis A: General

AU - MORI, TOHRU

AU - Kubo, Jun

AU - Morikawa, Yutaka

PY - 2004

DA - 2004/09/01

PB - Elsevier

SP - 69-76

IS - 1-2

VL - 271

SN - 0926-860X

SN - 1873-3875

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2004_MORI,

author = {TOHRU MORI and Jun Kubo and Yutaka Morikawa},

title = {Hydrodechlorination of 1,1,1-trichloroethane over silica-supported palladium catalyst},

journal = {Applied Catalysis A: General},

year = {2004},

volume = {271},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016/j.apcata.2004.02.047},

number = {1-2},

pages = {69--76},

doi = {10.1016/j.apcata.2004.02.047}

}

MLA

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MLA Copy

MORI, TOHRU, et al. “Hydrodechlorination of 1,1,1-trichloroethane over silica-supported palladium catalyst.” Applied Catalysis A: General, vol. 271, no. 1-2, Sep. 2004, pp. 69-76. https://doi.org/10.1016/j.apcata.2004.02.047.

Publisher

Elsevier

Journal

Applied Catalysis A: General

scimago Q2

wos Q2

SJR

1.000

CiteScore

8.6

Impact factor

4.8

ISSN

0926860X (Print)

18733875 (Electronic)