On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst
1
Interuniversity Consortium “Chemistry for the Environment” (INCA), via delle Industrie 21/8, 30175 Marghera (VE), Italy
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Publication type: Journal Article
Publication date: 2007-08-29
scimago Q1
wos Q1
SJR: 5.180
CiteScore: 38.4
Impact factor: 21.1
ISSN: 09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
Hydrodechlorination of 1,3,5-trichlorobenzene with hydrogen gas on Raney nickel catalyst in the biphasic system composed of isooctane, aqueous KOH, and a quaternary ammonium compound as a promoter at 70 °C and atmospheric pressure was studied. The promoter increased the rate of reaction above two orders of magnitude. Several quaternary chloride salts were studied, such as Aliquat 336, trioctylmethylammonium, tridodecylmethylammonium, cetyltrimethylammonium, tetrabutylammonium and tetraethylammonium. The relationship of the reaction rate with adsorption, micelle formation, and the structural properties of the promoter are discussed.
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ZINOVYEV S., Tundo P. On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst // Applied Catalysis B: Environmental. 2007. Vol. 75. No. 1-2. pp. 124-128.
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ZINOVYEV S., Tundo P. On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst // Applied Catalysis B: Environmental. 2007. Vol. 75. No. 1-2. pp. 124-128.
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TY - JOUR
DO - 10.1016/j.apcatb.2007.03.017
UR - https://doi.org/10.1016/j.apcatb.2007.03.017
TI - On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst
T2 - Applied Catalysis B: Environmental
AU - ZINOVYEV, S
AU - Tundo, Pietro
PY - 2007
DA - 2007/08/29
PB - Elsevier
SP - 124-128
IS - 1-2
VL - 75
SN - 0926-3373
SN - 1873-3883
ER -
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BibTex (up to 50 authors)
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@article{2007_ZINOVYEV,
author = {S ZINOVYEV and Pietro Tundo},
title = {On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst},
journal = {Applied Catalysis B: Environmental},
year = {2007},
volume = {75},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.apcatb.2007.03.017},
number = {1-2},
pages = {124--128},
doi = {10.1016/j.apcatb.2007.03.017}
}
Cite this
MLA
Copy
ZINOVYEV, S., and Pietro Tundo. “On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst.” Applied Catalysis B: Environmental, vol. 75, no. 1-2, Aug. 2007, pp. 124-128. https://doi.org/10.1016/j.apcatb.2007.03.017.