volume 87 issue 3-4 pages 211-219

Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride

T.F Garetto 1
C I Vignatti 1
A. Borgna 2
A. Monzón 3
Publication typeJournal Article
Publication date2009-04-07
scimago Q1
wos Q1
SJR5.180
CiteScore38.4
Impact factor21.1
ISSN09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride were studied. The effect of reactant partial pressures and temperature on the catalyst deactivation was investigated. A deactivation model with residual activity was developed to quantify the kinetic deactivation parameters. The effect of the regeneration atmosphere was also investigated. Regeneration under air allowed for the full recovery of the catalytic performance of fresh catalysts while treatments under flowing hydrogen resulted in a superior catalytic performance, increasing both the initial and residual activities. This was ascribed to a combined effect, redispersion of the metallic phase and formation of surface defects.
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GOST |
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GOST Copy
Garetto T. et al. Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride // Applied Catalysis B: Environmental. 2009. Vol. 87. No. 3-4. pp. 211-219.
GOST all authors (up to 50) Copy
Garetto T., Vignatti C. I., Borgna A., Monzón A. Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride // Applied Catalysis B: Environmental. 2009. Vol. 87. No. 3-4. pp. 211-219.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.apcatb.2008.09.005
UR - https://doi.org/10.1016/j.apcatb.2008.09.005
TI - Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride
T2 - Applied Catalysis B: Environmental
AU - Garetto, T.F
AU - Vignatti, C I
AU - Borgna, A.
AU - Monzón, A.
PY - 2009
DA - 2009/04/07
PB - Elsevier
SP - 211-219
IS - 3-4
VL - 87
SN - 0926-3373
SN - 1873-3883
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Garetto,
author = {T.F Garetto and C I Vignatti and A. Borgna and A. Monzón},
title = {Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride},
journal = {Applied Catalysis B: Environmental},
year = {2009},
volume = {87},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.apcatb.2008.09.005},
number = {3-4},
pages = {211--219},
doi = {10.1016/j.apcatb.2008.09.005}
}
MLA
Cite this
MLA Copy
Garetto, T.F, et al. “Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride.” Applied Catalysis B: Environmental, vol. 87, no. 3-4, Apr. 2009, pp. 211-219. https://doi.org/10.1016/j.apcatb.2008.09.005.