Gas-phase hydrodechlorination of mixtures of chloromethanes with activated carbon-supported platinum catalysts
Publication type: Journal Article
Publication date: 2015-12-01
scimago Q1
wos Q1
SJR: 5.180
CiteScore: 38.4
Impact factor: 21.1
ISSN: 09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
Platinum catalysts supported on activated carbon (Pt/C) at different metal loadings (0.5–2% Pt) have been tested in the gas-phase hydrodechlorination (HDC) of mixtures of dichloromethane (DCM) and chloroform (TCM), with a total feed concentration of 1000 ppm v . Almost complete dechlorination was achieved at 250 °C, 1 kg h mol −1 space time and a H 2 /CM molar ratio of 25 with the 2% Pt catalyst. At a reaction temperature of 250 °C, scarce inhibition in the conversion of both compounds was observed compared to the HDC of the individual chloromethanes. The TOF values for DCM increase with the Pt content, which can be attributed to the higher proportion of the zero-valent species. The selectivity to reaction products suggests a parallel reactions scheme. The catalysts showed a high stability, demonstrated by the unchanged conversion of both chloromethanes upon time on stream in long-term experiments carried out at up to 26 h.
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Arevalo Bastante A. et al. Gas-phase hydrodechlorination of mixtures of chloromethanes with activated carbon-supported platinum catalysts // Applied Catalysis B: Environmental. 2015. Vol. 179. pp. 551-557.
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Arevalo Bastante A., Álvarez Montero M. A., Bedia J., Gómez-Sainero L. M., Rodriguez J. J. Gas-phase hydrodechlorination of mixtures of chloromethanes with activated carbon-supported platinum catalysts // Applied Catalysis B: Environmental. 2015. Vol. 179. pp. 551-557.
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TY - JOUR
DO - 10.1016/j.apcatb.2015.05.058
UR - https://doi.org/10.1016/j.apcatb.2015.05.058
TI - Gas-phase hydrodechlorination of mixtures of chloromethanes with activated carbon-supported platinum catalysts
T2 - Applied Catalysis B: Environmental
AU - Arevalo Bastante, A
AU - Álvarez Montero, María Ariadna
AU - Bedia, Jorge
AU - Gómez-Sainero, Luisa Ma.
AU - Rodriguez, J. J.
PY - 2015
DA - 2015/12/01
PB - Elsevier
SP - 551-557
VL - 179
SN - 0926-3373
SN - 1873-3883
ER -
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@article{2015_Arevalo Bastante,
author = {A Arevalo Bastante and María Ariadna Álvarez Montero and Jorge Bedia and Luisa Ma. Gómez-Sainero and J. J. Rodriguez},
title = {Gas-phase hydrodechlorination of mixtures of chloromethanes with activated carbon-supported platinum catalysts},
journal = {Applied Catalysis B: Environmental},
year = {2015},
volume = {179},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.apcatb.2015.05.058},
pages = {551--557},
doi = {10.1016/j.apcatb.2015.05.058}
}