Elsevier
Applied Catalysis B: Environmental
,  том 351 ,  страницы 123999

Selective hydroprocessing of diphenyl ether into benzene over in situ generated MoOx and WOx

Тип публикации: Journal Article
Дата публикации: 2024-08-01
Elsevier
scimago Q1
wos Q1
БС1
SJR: 5.18
CiteScore: 38.4
Impact factor: 21.1
ISSN: 09263373, 18733883
Краткое описание
The catalytic activity of molybdenum and tungsten oxides formed in situ from their carbonyls was studied in the hydroprocessing of diphenyl ether (DPE) for the first time. The MoOx and WOx catalysts obtained were characterized by XRD, XPS, HRTEM, EDX, Raman spectroscopy, and NH3TPD. The effect of various parameters on the substrate conversion and the yields of products was investigated. Oxygen vacancies (OVs) on the catalyst surface were found to be active sites in the DPE hydroprocessing. MoOx was more active than WOx due to more OVs on the surface of the catalyst. Benzene was obtained as a major product over both of catalysts with a highest yield of 87% (99% DPE conversion) over MoOx and of 69% (96% DPE conversion) over WOx.
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Mukhtarova M. et al. Selective hydroprocessing of diphenyl ether into benzene over in situ generated MoOx and WOx // Applied Catalysis B: Environmental. 2024. Vol. 351. p. 123999.
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Mukhtarova M., Golubeva M. A., Sadovnikov A. A., Maximov A. Selective hydroprocessing of diphenyl ether into benzene over in situ generated MoOx and WOx // Applied Catalysis B: Environmental. 2024. Vol. 351. p. 123999.
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TY - JOUR
DO - 10.1016/j.apcatb.2024.123999
UR - https://linkinghub.elsevier.com/retrieve/pii/S0926337324003138
TI - Selective hydroprocessing of diphenyl ether into benzene over in situ generated MoOx and WOx
T2 - Applied Catalysis B: Environmental
AU - Mukhtarova, M
AU - Golubeva, Maria A
AU - Sadovnikov, A. A.
AU - Maximov, Anton
PY - 2024
DA - 2024/08/01
PB - Elsevier
SP - 123999
VL - 351
SN - 0926-3373
SN - 1873-3883
ER -
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@article{2024_Mukhtarova,
author = {M Mukhtarova and Maria A Golubeva and A. A. Sadovnikov and Anton Maximov},
title = {Selective hydroprocessing of diphenyl ether into benzene over in situ generated MoOx and WOx},
journal = {Applied Catalysis B: Environmental},
year = {2024},
volume = {351},
publisher = {Elsevier},
month = {aug},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0926337324003138},
pages = {123999},
doi = {10.1016/j.apcatb.2024.123999}
}