Applied Surface Science, volume 574, pages 151593

PVDF-HFP based polymer electrolytes with high Li+ transference number enhancing the cycling performance and rate capability of lithium metal batteries

YanYi Wang ^{1, 2}

Kaixiong Huang ³

Peixin Zhang ^{1, 2}

Haowen Li ⁴

Hongwei Mi ³

Hide authors affiliations Show authors affiliations: 4 affiliations

College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, PR China |

College of Materials Science and Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, PR China |

College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, 518060, PR China. |

⁴

Micro Optical Instruments (Shenzhen) Inc., Shenzhen 518118, PR China |

Publication type: Journal Article

Publication date: 2022-02-01

Elsevier

Journal: Applied Surface Science

Quartile SCImago

Quartile WOS

Impact factor: 6.7

ISSN: 01694332

DOI: 10.1016/j.apsusc.2021.151593

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Surfaces, Coatings and Films

General Chemistry

General Physics and Astronomy

Condensed Matter Physics

Surfaces and Interfaces

Abstract

• PVDF-HFP based polymer films possess good wettability and liquid retention ability. • GPEs present a high ionic conductivity of 1.82×10 −3 S·cm −1 at 25 °C. • The lithium ions transference number of GPEs is up to 0.513 at 25 °C. • LFP|GPEs|Li cell displays the capacity retention of 92% after 1000 cycles at 1 C. Lithium metal batteries are confronted with safety issues in liquid electrolyte systems owing to rapid growth of lithium dendrite and uneven lithium deposition. Exploration of gel polymer electrolytes (GPEs) with excellent ionic conductivity and high Li + migration number is a possible strategy to replace liquid electrolyte. Herein, a high-powered GPEs relied on poly (vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) modified by polymer polyethylene glycol (PEG) and lithium montmorillonite (LiMNT) via bond interactions is reported. The prepared porous polymer electrolyte presents a captivating ionic conductivity of 1.82 × 10 −3 S·cm −1 and lithium ions transference number up to 0.513 at 25 °C. In view of the eminent ionic conductivity and efficient migration number of Li + , the three-dimensional porous polymer electrolyte is very conducive to the fast transport and stable deposition of lithium ions, restraining the occurrence and growth rate of lithium dendrites, which improves the cycle performance and rate capability of lithium battery. LiFePO 4 | PPL122 electrolyte |Li battery delivers a desired cycling performance with a capacity retention of 92% after 1000 cycles at 1 C.

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Citations by journals

	1 2 3 4
Polymers	Polymers, 4, 7.69% Polymers 4 publications, 7.69%
ACS Applied Energy Materials	ACS Applied Energy Materials, 3, 5.77% ACS Applied Energy Materials 3 publications, 5.77%
Journal of Energy Storage	Journal of Energy Storage, 3, 5.77% Journal of Energy Storage 3 publications, 5.77%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 3.85% Chemical Engineering Journal 2 publications, 3.85%
Journal of Power Sources	Journal of Power Sources, 2, 3.85% Journal of Power Sources 2 publications, 3.85%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 2, 3.85% Journal of Alloys and Compounds 2 publications, 3.85%
Journal of the Taiwan Institute of Chemical Engineers	Journal of the Taiwan Institute of Chemical Engineers, 2, 3.85% Journal of the Taiwan Institute of Chemical Engineers 2 publications, 3.85%
Batteries	Batteries, 2, 3.85% Batteries 2 publications, 3.85%
InfoMat	InfoMat, 1, 1.92% InfoMat 1 publication, 1.92%
Chinese Journal of Polymer Science (English Edition)	Chinese Journal of Polymer Science (English Edition), 1, 1.92% Chinese Journal of Polymer Science (English Edition) 1 publication, 1.92%
Materials Chemistry and Physics	Materials Chemistry and Physics, 1, 1.92% Materials Chemistry and Physics 1 publication, 1.92%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 1.92% Journal of Colloid and Interface Science 1 publication, 1.92%
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 1, 1.92% Journal of Electroanalytical Chemistry 1 publication, 1.92%
Electrochimica Acta	Electrochimica Acta, 1, 1.92% Electrochimica Acta 1 publication, 1.92%
Carbohydrate Polymers	Carbohydrate Polymers, 1, 1.92% Carbohydrate Polymers 1 publication, 1.92%
Applied Surface Science	Applied Surface Science, 1, 1.92% Applied Surface Science 1 publication, 1.92%
Chinese Journal of Chemical Engineering	Chinese Journal of Chemical Engineering, 1, 1.92% Chinese Journal of Chemical Engineering 1 publication, 1.92%
Advanced Sustainable Systems	Advanced Sustainable Systems, 1, 1.92% Advanced Sustainable Systems 1 publication, 1.92%
SusMat	SusMat, 1, 1.92% SusMat 1 publication, 1.92%
Energy Storage	Energy Storage, 1, 1.92% Energy Storage 1 publication, 1.92%
ChemElectroChem	ChemElectroChem, 1, 1.92% ChemElectroChem 1 publication, 1.92%
Advanced Engineering Materials	Advanced Engineering Materials, 1, 1.92% Advanced Engineering Materials 1 publication, 1.92%
Molecules	Molecules, 1, 1.92% Molecules 1 publication, 1.92%
Macromolecular Materials and Engineering	Macromolecular Materials and Engineering, 1, 1.92% Macromolecular Materials and Engineering 1 publication, 1.92%
Discover Materials	Discover Materials, 1, 1.92% Discover Materials 1 publication, 1.92%
Materials Science and Engineering B: Solid-State Materials for Advanced Technology	Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 1, 1.92% Materials Science and Engineering B: Solid-State Materials for Advanced Technology 1 publication, 1.92%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 1.92% Journal of the Electrochemical Society 1 publication, 1.92%
Energies	Energies, 1, 1.92% Energies 1 publication, 1.92%
Green Chemistry	Green Chemistry, 1, 1.92% Green Chemistry 1 publication, 1.92%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12 14 16 18 20
Elsevier	Elsevier, 19, 36.54% Elsevier 19 publications, 36.54%
Wiley	Wiley, 8, 15.38% Wiley 8 publications, 15.38%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 8, 15.38% Multidisciplinary Digital Publishing Institute (MDPI) 8 publications, 15.38%
American Chemical Society (ACS)	American Chemical Society (ACS), 5, 9.62% American Chemical Society (ACS) 5 publications, 9.62%
Springer Nature	Springer Nature, 2, 3.85% Springer Nature 2 publications, 3.85%
Chemical Industry Press	Chemical Industry Press, 1, 1.92% Chemical Industry Press 1 publication, 1.92%
The Electrochemical Society	The Electrochemical Society, 1, 1.92% The Electrochemical Society 1 publication, 1.92%
Taiwan Institute of Chemical Engineers	Taiwan Institute of Chemical Engineers, 1, 1.92% Taiwan Institute of Chemical Engineers 1 publication, 1.92%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 1.92% Royal Society of Chemistry (RSC) 1 publication, 1.92%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.92% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.92%
	2 4 6 8 10 12 14 16 18 20

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Wang Y. et al. PVDF-HFP based polymer electrolytes with high Li+ transference number enhancing the cycling performance and rate capability of lithium metal batteries // Applied Surface Science. 2022. Vol. 574. p. 151593.

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Wang Y., Huang K., Zhang P., Li H., Mi H. PVDF-HFP based polymer electrolytes with high Li+ transference number enhancing the cycling performance and rate capability of lithium metal batteries // Applied Surface Science. 2022. Vol. 574. p. 151593.

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RIS Copy

TY - JOUR

DO - 10.1016/j.apsusc.2021.151593

UR - https://doi.org/10.1016/j.apsusc.2021.151593

TI - PVDF-HFP based polymer electrolytes with high Li+ transference number enhancing the cycling performance and rate capability of lithium metal batteries

T2 - Applied Surface Science

AU - Wang, YanYi

AU - Huang, Kaixiong

AU - Zhang, Peixin

AU - Li, Haowen

AU - Mi, Hongwei

PY - 2022

DA - 2022/02/01 00:00:00

PB - Elsevier

SP - 151593

VL - 574

SN - 0169-4332

ER -

BibTex

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BibTex Copy

@article{2022_Wang,

author = {YanYi Wang and Kaixiong Huang and Peixin Zhang and Haowen Li and Hongwei Mi},

title = {PVDF-HFP based polymer electrolytes with high Li+ transference number enhancing the cycling performance and rate capability of lithium metal batteries},

journal = {Applied Surface Science},

year = {2022},

volume = {574},

publisher = {Elsevier},

month = {feb},

url = {https://doi.org/10.1016/j.apsusc.2021.151593},

pages = {151593},

doi = {10.1016/j.apsusc.2021.151593}

}

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Publisher

Elsevier

Journal

Applied Surface Science

Quartile SCImago

Quartile WOS

Impact factor

6.7

ISSN

01694332 (Print)