volume 161 pages 486-494

Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition

Sergey I Belousov 1
Eugeny D Eidelman 2
Elena Yudina 2
Alexey A. Mikhutkin 1
A. V. Bakirov 3, 4
S. N. Chvalun 3, 4
Roman A. Kamyshinsky 4, 5, 6
Alexander Vasiliev 4, 5, 6
A. Mazur 7
Publication typeJournal Article
Publication date2020-05-01
scimago Q1
wos Q1
SJR2.320
CiteScore21.4
Impact factor11.6
ISSN00086223, 18733891
General Chemistry
General Materials Science
Abstract
The paper describes the data on unusual rheological properties of detonation nanodiamonds (DND) hydrosols and presents the fractal model explaining such behavior. The hydrosols of DND with particles size of 4–5 nm and concentration range of 1.1–7.3 wt% with negative (ζ   0) electrokinetic potentials have been studied by rotational viscometry, small-angle X-ray scattering, nuclear magnetic resonance and Cryo Electron Tomography. Remarkable hysteresis of viscosity and thixotropic effect demonstrate the sol-gel transition at very low concentrations of the DND: 4–5 wt% for ζ > 0 and 5–6 wt% for ζ
Found 
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GOST Copy
Kuznetsov N. M. et al. Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition // Carbon. 2020. Vol. 161. pp. 486-494.
GOST all authors (up to 50) Copy
Kuznetsov N. M., Belousov S. I., Eidelman E. D., Yudina E., Mikhutkin A. A., Bakirov A. V., Chvalun S. N., Kamyshinsky R. A., Vasiliev A., Tolstoy P. M., Mazur A., Vul' A. Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition // Carbon. 2020. Vol. 161. pp. 486-494.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.carbon.2020.01.054
UR - https://doi.org/10.1016/j.carbon.2020.01.054
TI - Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition
T2 - Carbon
AU - Kuznetsov, N. M.
AU - Belousov, Sergey I
AU - Eidelman, Eugeny D
AU - Yudina, Elena
AU - Mikhutkin, Alexey A.
AU - Bakirov, A. V.
AU - Chvalun, S. N.
AU - Kamyshinsky, Roman A.
AU - Vasiliev, Alexander
AU - Tolstoy, Peter M.
AU - Mazur, A.
AU - Vul', A.Ya.
PY - 2020
DA - 2020/05/01
PB - Elsevier
SP - 486-494
VL - 161
SN - 0008-6223
SN - 1873-3891
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Kuznetsov,
author = {N. M. Kuznetsov and Sergey I Belousov and Eugeny D Eidelman and Elena Yudina and Alexey A. Mikhutkin and A. V. Bakirov and S. N. Chvalun and Roman A. Kamyshinsky and Alexander Vasiliev and Peter M. Tolstoy and A. Mazur and A.Ya. Vul'},
title = {Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition},
journal = {Carbon},
year = {2020},
volume = {161},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.carbon.2020.01.054},
pages = {486--494},
doi = {10.1016/j.carbon.2020.01.054}
}