Carbon, volume 187, pages 13-21

In situ construction of a flexible interlayer for durable solid-state lithium metal batteries

Naixuan Ci 1
Lin Zhang 1
Jianwei Li 1
Jun Cheng 2
Qing Sun 1
Zhenjie Xi 1
Zhou Xu 1
Guoqing Zhao 1
Lijie Ci 3
Publication typeJournal Article
Publication date2022-02-01
Journal: Carbon
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor10.9
ISSN00086223
General Chemistry
General Materials Science
Abstract
The development of solid-state lithium-metal batteries (SSLMBs) is severely constrained by the poor physical and (electro)chemical stability of the interface between solid-state electrolytes (SSEs) and lithium (Li) metal anode. Here, a flexible rGO film with uniformly distributed ZnO is in situ constructed at the interface between NASICON-type Li 1.5 Al 0.5 Ge 0.5 (PO 4 ) 3 (LAGP) and Li metal anode. Such a buffer layer realizes a good interfacial contact, and prevents the side reaction between the Li metal anode and LAGP. As a result, the symmetric cells with the designed structure present a high critical current density of 3.0 mA cm ˗2 and stable cycling for over 800 h at 0.15 mA cm ˗2 . In addition, LiFePO 4 (LFP)/Li full batteries deliver excellent capacity retention and long cycling performance. An in situ formed rGO/ZnO (GZO) flexible film is designed to modify the LAGP/Li interface. The citical current density (CCD) of the Li/GZO@LAGP/Li symmetric cell is substantially improved to 3.0 mA cm ˗2 at 25 °C.

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GOST Copy
Ci N. et al. In situ construction of a flexible interlayer for durable solid-state lithium metal batteries // Carbon. 2022. Vol. 187. pp. 13-21.
GOST all authors (up to 50) Copy
Ci N., Zhang L., Li J., Cheng J., Sun Q., Xi Z., Xu Z., Zhao G., Ci L. In situ construction of a flexible interlayer for durable solid-state lithium metal batteries // Carbon. 2022. Vol. 187. pp. 13-21.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.carbon.2021.10.070
UR - https://doi.org/10.1016/j.carbon.2021.10.070
TI - In situ construction of a flexible interlayer for durable solid-state lithium metal batteries
T2 - Carbon
AU - Ci, Naixuan
AU - Zhang, Lin
AU - Li, Jianwei
AU - Ci, Lijie
AU - Cheng, Jun
AU - Sun, Qing
AU - Xi, Zhenjie
AU - Xu, Zhou
AU - Zhao, Guoqing
PY - 2022
DA - 2022/02/01 00:00:00
PB - Elsevier
SP - 13-21
VL - 187
SN - 0008-6223
ER -
BibTex
Cite this
BibTex Copy
@article{2022_Ci,
author = {Naixuan Ci and Lin Zhang and Jianwei Li and Lijie Ci and Jun Cheng and Qing Sun and Zhenjie Xi and Zhou Xu and Guoqing Zhao},
title = {In situ construction of a flexible interlayer for durable solid-state lithium metal batteries},
journal = {Carbon},
year = {2022},
volume = {187},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.carbon.2021.10.070},
pages = {13--21},
doi = {10.1016/j.carbon.2021.10.070}
}
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