Open Access
Promotional effect of magnesia addition to active carbon supported Pd catalyst on the characteristics and hydrodechlorination activity of CCl2F2
Publication type: Journal Article
Publication date: 2004-03-01
scimago Q1
wos Q2
SJR: 0.811
CiteScore: 7.9
Impact factor: 4.3
ISSN: 15667367
General Chemistry
Catalysis
Process Chemistry and Technology
Abstract
Magnesia modified active carbon supported palladium (Pd–MgO/C) catalyst prepared by co-impregnation, has shown superior activity in the hydrodechlorination of CCl 2 F 2 to produce CH 2 F 2 in greater yields compared to Pd/C and Pd/MgO catalysts. The high activity of Pd–MgO/C catalyst is due to the synergistic effect of Pd/C and Pd/MgO components. CO chemisorption results indicate the formation of bigger particles of Pd in Pd–MgO/C catalyst and the formation of MgF 2 from MgO (on reaction with HF released during the reaction), induce electron deficient surface so that the rate of the desorption of intermediate CF 2 ∗ adsorbed species is more facile yielding CH 2 F 2 .
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14
Total citations:
14
Citations from 2024:
2
(14.28%)
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GOST
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Krishna Murthy J. et al. Promotional effect of magnesia addition to active carbon supported Pd catalyst on the characteristics and hydrodechlorination activity of CCl2F2 // Catalysis Communications. 2004. Vol. 5. No. 3. pp. 161-167.
GOST all authors (up to 50)
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Krishna Murthy J., Chandra Shekar S., Padmasri A., Akula V., Siva Kumar V., Nagaraja B., Shashikala V., Raju B., Kanta Rao P., Rao K. J. Promotional effect of magnesia addition to active carbon supported Pd catalyst on the characteristics and hydrodechlorination activity of CCl2F2 // Catalysis Communications. 2004. Vol. 5. No. 3. pp. 161-167.
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RIS
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TY - JOUR
DO - 10.1016/j.catcom.2003.11.014
UR - https://doi.org/10.1016/j.catcom.2003.11.014
TI - Promotional effect of magnesia addition to active carbon supported Pd catalyst on the characteristics and hydrodechlorination activity of CCl2F2
T2 - Catalysis Communications
AU - Krishna Murthy, J.
AU - Chandra Shekar, S.
AU - Padmasri, A.H.
AU - Akula, Venugopal
AU - Siva Kumar, V.
AU - Nagaraja, B.M.
AU - Shashikala, V.
AU - Raju, B.David
AU - Kanta Rao, P.
AU - Rao, K.S. Jagannatha
PY - 2004
DA - 2004/03/01
PB - Elsevier
SP - 161-167
IS - 3
VL - 5
SN - 1566-7367
ER -
Cite this
BibTex (up to 50 authors)
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@article{2004_Krishna Murthy,
author = {J. Krishna Murthy and S. Chandra Shekar and A.H. Padmasri and Venugopal Akula and V. Siva Kumar and B.M. Nagaraja and V. Shashikala and B.David Raju and P. Kanta Rao and K.S. Jagannatha Rao},
title = {Promotional effect of magnesia addition to active carbon supported Pd catalyst on the characteristics and hydrodechlorination activity of CCl2F2},
journal = {Catalysis Communications},
year = {2004},
volume = {5},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.catcom.2003.11.014},
number = {3},
pages = {161--167},
doi = {10.1016/j.catcom.2003.11.014}
}
Cite this
MLA
Copy
Krishna Murthy, J., et al. “Promotional effect of magnesia addition to active carbon supported Pd catalyst on the characteristics and hydrodechlorination activity of CCl2F2.” Catalysis Communications, vol. 5, no. 3, Mar. 2004, pp. 161-167. https://doi.org/10.1016/j.catcom.2003.11.014.