Open Access
New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol
Publication type: Journal Article
Publication date: 2015-01-01
scimago Q1
wos Q2
SJR: 0.811
CiteScore: 7.9
Impact factor: 4.3
ISSN: 15667367
General Chemistry
Catalysis
Process Chemistry and Technology
Abstract
Transitional metal phosphides were found to have outstanding activity and stability in catalytic hydrotreatments. The bulk trinickel phosphide catalyst with the smallest phosphorus content among the nickel phosphides were synthesized by a hydrothermal method followed by an annealing treatment, and the resulting bulk trinickel phosphide catalysts presented a high purity and morphology of hexagonal prisms. The optimized synthesis conditions include a P:Ni ratio of 3 to 1 and a pH value of 5 in the hydrothermal synthesis stage and a calcination temperature of 773 K in the annealing treatment. The synthesized trinickel phosphides exhibited a low-temperature activity to selective glycerol hydrogenolysis and the high selectivity to 1,2-propanediol.
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16
Total citations:
16
Citations from 2024:
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(6.25%)
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GOST
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Shi G., SU L., Jin K. New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol // Catalysis Communications. 2015. Vol. 59. pp. 180-183.
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Shi G., SU L., Jin K. New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol // Catalysis Communications. 2015. Vol. 59. pp. 180-183.
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RIS
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TY - JOUR
DO - 10.1016/j.catcom.2014.10.020
UR - https://doi.org/10.1016/j.catcom.2014.10.020
TI - New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol
T2 - Catalysis Communications
AU - Shi, Guojun
AU - SU, LIJUN
AU - Jin, Kai
PY - 2015
DA - 2015/01/01
PB - Elsevier
SP - 180-183
VL - 59
SN - 1566-7367
ER -
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BibTex (up to 50 authors)
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@article{2015_Shi,
author = {Guojun Shi and LIJUN SU and Kai Jin},
title = {New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol},
journal = {Catalysis Communications},
year = {2015},
volume = {59},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.catcom.2014.10.020},
pages = {180--183},
doi = {10.1016/j.catcom.2014.10.020}
}