Open Access
Hydroisomerization of hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradecanes to diamantane induced by ionic liquids
Publication type: Journal Article
Publication date: 2019-10-01
scimago Q1
wos Q2
SJR: 0.811
CiteScore: 7.9
Impact factor: 4.3
ISSN: 15667367
General Chemistry
Catalysis
Process Chemistry and Technology
Abstract
Hydroisomerization of endo-endo-, exo-exo-, exo-endo-, and endo-exo-, hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradecanes to diamantane was performed for the first time in 80–96% yields under the action of ionic liquids (ILs), [Et3NH]+[Al2Cl7]− and [BMIM]+[Fe2Cl7]−. Ionic liquids have multiple functions, promoting the following reactions of hexacyclotetradecanes: hydrogenation, dehydrogenation, and skeletal rearrangement; simultaneously, they serve as HCl donors.
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Aminov R. I., Akshieva A. N., Khusnutdinov R. I. Hydroisomerization of hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradecanes to diamantane induced by ionic liquids // Catalysis Communications. 2019. Vol. 130. p. 105756.
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Aminov R. I., Akshieva A. N., Khusnutdinov R. I. Hydroisomerization of hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradecanes to diamantane induced by ionic liquids // Catalysis Communications. 2019. Vol. 130. p. 105756.
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TY - JOUR
DO - 10.1016/j.catcom.2019.105756
UR - https://doi.org/10.1016/j.catcom.2019.105756
TI - Hydroisomerization of hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradecanes to diamantane induced by ionic liquids
T2 - Catalysis Communications
AU - Aminov, Rishat I
AU - Akshieva, Aida N
AU - Khusnutdinov, Ravil I
PY - 2019
DA - 2019/10/01
PB - Elsevier
SP - 105756
VL - 130
SN - 1566-7367
ER -
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@article{2019_Aminov,
author = {Rishat I Aminov and Aida N Akshieva and Ravil I Khusnutdinov},
title = {Hydroisomerization of hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradecanes to diamantane induced by ionic liquids},
journal = {Catalysis Communications},
year = {2019},
volume = {130},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.catcom.2019.105756},
pages = {105756},
doi = {10.1016/j.catcom.2019.105756}
}
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