Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts
2
Criminal Investigation Laboratory, Metropolitan Police Department, 2-1-1 Kasumigaseki, Chiyoda, Tokyo 100-8929, Japan
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Publication type: Journal Article
Publication date: 2005-10-01
scimago Q1
wos Q1
SJR: 1.050
CiteScore: 11.2
Impact factor: 5.3
ISSN: 09205861, 18734308
General Chemistry
Catalysis
Abstract
The activity of nickel molybdenum phosphide catalysts was studied for the hydrodesulfurization of dibenzothiophene at 573 K and total pressure of 2.0 MPa. The Al 2 O 3 -supported NiMo phosphide catalysts were prepared by successive and simultaneous methods. The effect of the reduction temperature on the catalyst activity was also studied. The simultaneous preparation was determined to be the best method for the preparation of the active supported catalyst for dibenzothiophene HDS. The 623 K-reduced catalyst had the highest HDS rate of the catalysts. Nickel migrated from the inside to the surface during the reaction and promoted the HDS activity. The active species in the dibenzothiophene HDS and the oxidation states of Mo, Ni and P in the catalyst before and after reaction and of S after the reaction were studied on the basis of an XPS analysis.
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Total citations:
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Citations from 2024:
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(10.71%)
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GOST
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Nagai M., Fukiage T., Kurata S. Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts // Catalysis Today. 2005. Vol. 106. No. 1-4. pp. 201-205.
GOST all authors (up to 50)
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Nagai M., Fukiage T., Kurata S. Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts // Catalysis Today. 2005. Vol. 106. No. 1-4. pp. 201-205.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.cattod.2005.07.130
UR - https://doi.org/10.1016/j.cattod.2005.07.130
TI - Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts
T2 - Catalysis Today
AU - Nagai, Masatoshi
AU - Fukiage, Tomokazu
AU - Kurata, Shoji
PY - 2005
DA - 2005/10/01
PB - Elsevier
SP - 201-205
IS - 1-4
VL - 106
SN - 0920-5861
SN - 1873-4308
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Nagai,
author = {Masatoshi Nagai and Tomokazu Fukiage and Shoji Kurata},
title = {Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts},
journal = {Catalysis Today},
year = {2005},
volume = {106},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.cattod.2005.07.130},
number = {1-4},
pages = {201--205},
doi = {10.1016/j.cattod.2005.07.130}
}
Cite this
MLA
Copy
Nagai, Masatoshi, et al. “Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts.” Catalysis Today, vol. 106, no. 1-4, Oct. 2005, pp. 201-205. https://doi.org/10.1016/j.cattod.2005.07.130.